Summary

John William Strutt 1911 Encyclopædia Britannica, Volume 25… (1911)

The Colour of the Sky.—It is a matter of common observation that the blue of the sky is highly variable, even on days that are free from clouds. The colour usually deepens toward the zenith and also with the elevation of the observer. It is evident that the normal blue is more or less diluted with extraneous white light, having its origin in reflections from the grosser particles of foreign matter with which the air is usually charged. Closely associated with the colour is the polarization of the light from the sky.
Source: Wikisource

John William Strutt 1911 Encyclopædia Britannica, Volume 25… (1911)

So long as the particles are all very small in comparison with the wave-length, there is complete polarization in the perpendicular direction; but when the size is such that obliquity sets in, the degree of obliquity will vary with the size of the particles, and the polarization will be complete only on the very unlikely condition that the size is the same for them all. It must not be forgotten, too, that a very moderate increase of dimensions may carry the particles beyond the reach of our approximations.
Source: Wikisource

John William Strutt 1911 Encyclopædia Britannica, Volume 25… (1911)

About the colour there can be no prima facie difficulty; for, as soon as the question is raised, it is seen that the standard of linear dimension, with reference to which the particles are called small, is the wave-length of light, and that a given set of particles would (on any conceivable view as to their mode of action) produce a continually increasing disturbance as we pass along the spectrum towards the more refrangible end.
Source: Wikisource

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