Summary

1911 Encyclopædia Britannica, Volume 6… (1911)

In making the acid by this process benzaldehyde, acetic anhydride and anhydrous sodium acetate are heated for some hours to about 1800 C, the resulting product is made alkaline with sodium carbonate, and any excess of benzaldehyde removed by a current of steam. The residual liquor is filtered and acidified with hydrochloric acid, when cinnamic acid is precipitated, C6H5CHO+CH3COONa = C6H5CH:CH.COONa + H2O. It may be purified by recrystallization from hot water.
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