Summary

1911 Encyclopædia Britannica, Volume 17… (1911)

It burns with a pale flame, and when mixed with air or oxygen forms a highly explosive mixture. W. A. Bone (Jour. Chem. Soc., 1902, 81, p. 535; 1903, 83, p. 1074) has shown that in the oxidation of methane by oxygen at 450–500° C. formaldehyde (or possibly methyl alcohol) is formed as an intermediate product, and is ultimately oxidized to carbon dioxide. Methane is an exceedingly stable gas, being unaffected by the action of chromic acid, nitric acid, or a mixture of nitric and sulphuric acids.
Source: Wikisource

1911 Encyclopædia Britannica, Volume 17… (1911)

It may be synthetically obtained by passing a mixture of the vapour of carbon bisulphide with sulphuretted hydrogen over red-hot copper (M. Berthelot, Comptes rendus, 1856, 43, p. 236) , CS2 + 2H2S + 8Cu = 4Cu2S + CH4; by passing a mixture of hydrogen and carbon monoxide over reduced nickel at 200–250° C., or hydrogen and carbon dioxide at 230–300° C. (P. Sabatier and J. B. Senderens, Comptes rendus, 1902, 134, pp. 514, 689)
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