Summary

1911 Encyclopædia Britannica, Volume 6… (1911)

They are all decomposed on heating, with evolution of oxygen; and in contact with concentrated sulphuric acid with liberation of chlorine peroxide. The most important is potassium chlorate, KClO3, which was obtained in 1786 by C. L. Berthollet by the action of chlorine on caustic potash, and this method was at first used for its manufacture. The modern process consists in the electrolysis of a hot solution of potassium chloride, or, preferably, the formation of sodium chlorate by the electrolytic method and its subsequent decomposition by potassium chloride.
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