Alfred Nobel,
British Patent 27197 (1896) — An improved manufacture of explosive compounds
“ This invention relates to the manufacture of a smokeless explosive compound, consisting of layers of powder of different chemical compositions, which are of such a nature, and are so arranged relatively to each other, that the combustion is slowest in the outer layer, and increases inwards. The object of this invention is to modify the pressure in the powder chamber and adjacent parts of the guns in which the explosive compound is used, which pressure has a tendency to rise to a dangerous point, owing to the charge being confined in a contracted space. ”
