Svante Arrhenius,
On the Influence of Carbonic Acid in the Air upon the Temperature of the Earth
(1897)
“ As the enormous quantities of carbonic acid (representing a pressure of many atmospheres) that are now fixed in the limestone of the Earth's crust cannot be conceived to have existed in the air but as an insignificant fraction of the whole at any one time since organic life appeared on the globe, and since therefore the consumption through weathering and formation of carbonates must have been compensated by means of continuous supply, we must regard volcanic exhalations as the chief source of carbonic acid for the atmosphere. ”
