1911 Encyclopædia Britannica, Volume 11… (1911)
“ Germanium compounds on fusion with alkaline carbonates and sulphur form salts known as thiogermanates. If excess of a mineral acid be added to a solution of an alkaline thiogermanate a white precipitate of germanium disulphide, GeS2, is obtained. It can also be obtained by passing sulphuretted hydrogen through a solution of the dioxide in hydrochloric acid. It is appreciably soluble in water, and also in solutions of the caustic alkalis and alkaline sulphides. By heating the disulphide in a current of hydrogen, germanious sulphide, GeS, is formed. ”
