Rufus P. Williams

“ This explains why salts are usually inactive and neutral in character, while acids and bases are active agents. Thus we see why the most positive or the most negative elements in general have the strongest affinities, while those intermediate in the list are inactive, and have weak affinities; why alloys of the metals are weak compounds; why a neutral substance, like water, has such a weak affinity for the salts which it holds in solution; and why an aqueous solution is regarded as a mechanical mixture rather than a chemical compound. ”

“ Of which is the sugar experiment an example? Metathesis is an exchange of atoms in two different compounds; it gives rise to still other compounds.
A chemical change may add something to a substance, or subtract something from it, or it may both subtract and add, making a new substance with entirely different properties. Sulphur and carbon are two stable solids. The chemical union of the two forms a volatile liquid. A substance may be at one time a solid, at another a liquid, at another a gas, and yet not undergo any chemical change, because in each case the chemical composition is identical. ”

“ Light and Heat of Flame.—Which of the two flames is hotter, the one with the air-holes open, or that with them closed? Evidently the former; for air is drawn in and mixes with the gas as it rises in the tube, and, on reaching the flame at the top, the two are well mingled, and the gaseous compounds of C and H burn at so high a temperature that solid C is not freed; hence there is little light. On closing the air-holes, no O can reach the flame except from the outside, and the heat is much less intense. ”

“ Water is the leading compound in both animals and plants. One of the most important differences between animals and plants is, that all plants, except parasitic ones, are capable of building up such compounds as starch from mineral food-stuffs, while animals have not that power, but must have the products of proximate analysis ready prepared, as it were, by the plant. Hence plants thrive on minerals, whereas animals feed on plants or on other animals. The power which plants have of transforming mineral matter is largely due to sunlight, the action of which in separating CO, was described. ”

“ A mass is any portion of a substance larger than a molecule; it is an aggregation of molecules.
A molecule is the smallest particle of a substance that can exist alone.
A substance in solution may be in a more finely divided state than otherwise, but it is not necessarily in its ultimate state of division.
7. A Chemical Change.—Cannot this smallest particle of sugar, the molecule, be separated into still smaller particles of something else? May it not be a compound body, and will not some force separate it into two or more substances? The next experiment will answer the question. ”

“ Conservation.—Plants, in growing, decompose CO2, and thereby store up energy, the energy derived from the light and heat of the sun. When they decay, or are burned, or are eaten by animals, exactly the same amount of energy is liberated, or changed from potential to kinetic, and the same amount of CO2 is restored to the air. The tree that took a hundred years to complete its growth may be burned in an hour, or be many years in decaying ”

“ In fact, there are indications that the present theory of atoms and molecules of matter, as the foundation of chemistry, will at no distant day give place to a theory of chemistry based on the forms of energy, of which heat is a manifestation. ”

“ If there be less pressure, as on a mountain, the boiling-point is lowered below 100 degrees. Salts dissolved in water raise its boiling-point, and lower its freezing-point to an extent depending on the kind and quantity of the salt. Water, however, evaporates at all temperatures, even from ice.
Pure water has no taste or smell, and, in small quantities, no color. It is rarely if ever found on the earth. What is taken up by the air in evaporation is nearly pure; but when it falls as rain or snow, impurities are absorbed from the atmosphere. ”

“ Liquefaction and Solidification of Gases.—Water boils at 100 degrees, under standard pressure, though evaporating at all temperatures; it vaporizes at a lower point if the pressure be less, as on a mountain, and at a higher temperature if the pressure be greater, as at points below the sea level. Alcohol boils at 78 degrees, standard pressure, and every liquid has a point of temperature and pressure above which it must pass into the gaseous state. Likewise every gas has a critical temperature above which it cannot be liquefied at any pressure. ”

“ CO2 is the deadly "choke damp" after a mine explosion, CH4 being converted into CO2 and H2O; a great deal is liberated during volcanic eruptions, and it is formed in breathing by the union of O in the air with C in the system. This union of C and O takes place in the lungs and in all the tissues of the body, even on the surface. Oxygen is taken into the lungs, passes through the thin membrane into the blood, forms a weak chemical union with the red corpuscles, and is conveyed by them to all parts of the system. ”

“ However large the masses changed by chemical action, that action is always on the individual molecule, the atoms of which are separated. If the molecule were an indivisible particle, no science of chemistry would be possible. The physicist finds the properties of masses of matter and resolves them into molecules, the chemist breaks up the molecule and from its atoms builds up other compounds. ”

“ Millions of years ago trees and other vegetation covered the earth as they do to-day. In certain places they slowly sank, together with the land, into the interior of the earth, were covered with sand, rock, and water, and heated from the earth's interior. A slow distillation took place, which drove off some of the gases, and converted vegetable matter into coal. All the coal dug from the earth represents vegetable life of a former period. ”

“ Na-Cl. The element Mg, however, has two such bonds, as Mg= or -Mg-. When Mg unites with Cl, in order to balance, or saturate, the bonds, it is evident that two atoms of Cl must be used, as Cl-Mg-Cl, or MgCl2.
A compound or an element, in order to exist, must have no free bonds. In organic chemistry the exceptions to this rule are very numerous, and, in fact, we do not know that atoms have bonds at all; but we can best explain the phenomena by supposing them, and for a general statement we may say that there must be no free bonds. In binaries the bonds of each element must balance. ”

“ It is easy to fancy that all living bodies, both animal and vegetable, are only natural growths from the lowest forms of life; that these lowest forms are a development, with new manifestations of energy, from inorganic matter; that compounds are derived from elements; and that the last are derivatives of some one element; but it must be borne in mind that this is only a theory.
342. New Theory of Chemistry. We have seen that heat lies at the basis of chemical as well as of physical changes. ”

“ One metal may be said to dissolve in the other, as sugar dissolves in water. The alloy has, however, different properties from those of its elements. For example, plumber's solder melts at a lower temperature than either Ph or Sn, of which it is composed. Some metals can alloy in any proportions. Solder may have two parts of Sn to one of Pb, two of Pb to one of Sn, or equal parts of each, or the two elements may alloy in other proportions. Not all metals can be thus fused together indefinitely; e.g., Zn and Pb. Nickel and silver coins are alloyed with Cu, gold coins with Cu and Ag. ”

“ In organic as in inorganic chemistry, atoms are bound together by chemical affinity, though it was formerly supposed that an additional or vital force was instrumental in forming organic compounds. For this reason none of these substances, it was thought, could be built up in the laboratory, although many had been analyzed. In 1828 the first organic compound, urea, was artificially prepared, and since then thousands have been synthesized. They are not necessarily manufactured from organic products, but can be made from mineral matter. ”

“ A third is consumed in uniting with the substance which it oxidizes, while two-thirds are changed into oxygen, as in Experiment 79.
It is unhealthful to breathe much ozone, but a little in the air is desirable for disinfection.
Ozone will cause the inert N of the air to unite with H, to form ammonia. No other agent capable of doing this is known, so that all the NH3 in the air, in fact all ammonium compounds taken up by plants from soils and fertilizers, may have been made originally through the agency of ozone. At a low temperature ozone has been liquefied. ”

“ Ammonium, NH4, is too unstable to exist alone, but it forms salts similar to those of K and Na. NH3 dissolved in water forms NH4OH.
The food of plants, as well as that of animals, must contain N. It has not yet been shown that they can make use of that contained in the air, but they do absorb its compounds from the soil. All fertilizers and manures contain a soluble compound of NH4. All NH4 compounds are now obtained either from coal, in making illuminating-gas, or from bones, by distillation. ”

“ These germs do not spring into life spontaneously from inorganic matter, but come from pre-existent similar forms. Parasites are not so rare in the system even of a healthy person as is generally supposed. They are found on our teeth and in many of the tissues of the body.
Several infectious diseases are now warded off or rendered less virulent by vaccination, the philosophy of which is that the organisms are rendered less dangerous by domestication; several crops, or generations, are grown in a prepared liquid, each less injurious than its parent. ”

“ If, as in some fevers, the temperature rises above about 105 degrees F., the blood corpuscles are killed, and the person dies. During violent exercise much material is consumed, circulation is rapid, and quick breathing ensues. Oxygen is necessary for life. A healthy person inhales plentifully; and this element is one of nature's best remedies for disease. Deep and continued inhalations in cold weather are better than furnace fires to heat the system. All animals breathe O and exhale CO2. Fishes and other aquatic animals obtain it, not by decomposing H2O, but from air dissolved in water. ”

“ Organic chemistry was formerly defined as the chemistry of the compounds found in plants and animals; but of late it has taken a much wider range, and is now defined as the chemistry of the C compounds, since C is the nucleus around which other elements centre, and with which they combine to form the organic substances. New organic compounds are constantly being discovered and synthesized, so that nearly 100,000 are now known. The molecule of organic matter is often very complex, sometimes containing hundreds of atoms. ”

“ Platinum is much rarer than gold, and is about two-thirds as costly as the latter. It is found alloyed with other metals, as An, and is obtained from sand, in which it occurs, by washing. Aqua regia is the only acid which dissolves it, and the action is much slower than with Au. Pt is one of the heaviest metals, having a specific gravity three times that of Fe, or twenty-one and a half times that of water. Its fusing-point is about 1600 degrees, or just below the temperature of the oxy-hydrogen flame. Like Au it has little affinity for other elements, but alloys with many metals. ”

“ Green plants—those containing chlorophyll— manufacture their own starch from CO2 and H2O. These chlorophyll grains are the plant's chemical laboratories, and hundreds of thousands of them exist in every leaf. CO2 and a very little H2O enter the leaf from the air, H2O being also drawn up through the root and stem from the earth. In some unknown way in the leaf, light has the power of synthesizing these into starch and setting free O, which is returned to the atmosphere.6 CO2 + 5 H2O = C6H10O5 + 12 O. As no such change takes place in darkness, all green plants must have light. ”