Zinc

“ Zinc itself is readily soluble in dilute acids; any residue which is left after boiling with dilute hydrochloric or sulphuric acid consists simply of the impurities of the metal; this is generally lead.
All zinc compounds are either soluble in, or are decomposed by, boiling with acids, the zinc going into solution. Zinc forms only one series of salts, and these are colourless. Their chief characteristic is solubility in an alkaline solution, from which sulphuretted hydrogen produces a white precipitate of zinc sulphide. ”

“ Zinc is detected by dissolving the substance in hydrochloric or nitric acid, boiling, and adding sodic hydrate in excess, filtering, and adding ammonic sulphide to the filtrate. The precipitate contains the zinc, which can be dissolved out by boiling with dilute sulphuric acid, and detected by the formation of a white precipitate on the addition of potassic ferrocyanide.
The dry assay of zinc can only be made indirectly, and is unsatisfactory. Zinc is volatile, and at the temperature of its reduction is a gas. ”

“ Zinc (Zn) .—This metal is found in considerable abundance, but never occurs in the pure metallic state, but in combination with other substances, chiefly as sulphide in zinc blende, as carbonate in calamine, and as the silicate in the kieselzinc ore; also, with sulphuric acid, the "vitriol of zinc."
Zinc is of a bluish-white color and metallic lustre, is crystalline and brittle when heated 400°F., but malleable and ductile between 200° and 300°. It will not oxidize in dry air, but tarnishes if exposed to air containing moisture, first becomes grey, and then passes into the white carbonate. ”

“ Many of our domestic utensils, particularly those which serve for the holding of liquids, are now made of zinc. Large quantities are moulded into architectural ornaments; and the splendid white colour of the oxide of zinc has made it a triumphant rival of ceruse, or white-lead. ”

“ The advantages of the zinc method are, that it is easily worked and that the excess of zinc is readily removed by simply filtering. The disadvantages are the slowness [68] with which the last portions of ferric iron are reduced, the danger of loss by effervescence, the precipitation of basic salts, and, perhaps, of iron, and the loading of the solution with salts of zinc, which in the titration with bichromate have a prejudicial effect. ”

“ Zinc white is, when compared with lead, quite light in weight, or, in other words, its volume is much greater than lead. Now, it being an entirely different product, it must not be treated in the same way as lead would be. The painter, perhaps, takes some zinc, mixes it with raw oil, with a liberal amount of patent driers and a more liberal dose of turpentine, and then he grumbles because it does not show up to advantage. What he does is to destroy its inherent good qualities. To repeat then, zinc white must not be treated in the same way as white lead. ”

“ Zinc, free from other metals, may be obtained by distilling a mixture of charcoal and its subcarbonate, precipitated from the crystallized sulphate by carbonate of soda. By holding a porcelain saucer over the flame of hydrogen produced from the action of dilute sulphuric acid upon any sample of the zinc of commerce, the presence of arsenic in it may be made manifest by the deposit of a gray film of the latter metal. Antimony, however, produces a somewhat similar effect to arsenic. ”

“ Preparation of pure Oxide of Zinc, by M. Hermann.—It is by no means easy to obtain this substance perfectly pure; the following is M. Hermann’s process: Oxide of zinc, or metallic zinc, is to be dissolved in excess of sulphuric acid, and the solution being filtered, sulphuretted hydrogen is to be passed through, so long as a brown or yellow precipitate is formed. Cadmium, lead, or copper, being thus separated, and the solution filtered, it is to be treated with solution of the chloride of lime, (bleaching powder,) by which the iron and manganese will be separated. ”

“ Then attach a small piece of zinc by a string to the cork or stopper of the bottle, so that the zinc shall hang about the middle of the bottle, and set it by where it may be quite undisturbed. In a short time brilliant plates of silver or lead, as the case may be, will be seen to collect around the piece of zinc, assuming more or less of the crystalline form. This is a case of elective affinity; the acid with which the silver or lead was united prefers the zinc to either of those metals, and in consequence discards them in order to attach the zinc to itself ”

“ More than 80 per cent. of the amount annually made in Germany is used for the production of zinc green by mixing with Prussian blues, of which substance Holland, Switzerland, and Hungary are the greatest consumers. The zinc yellows met with in commerce vary in their constitution considerably, being usually acid chromates of zinc and potassium, basic zinc chromates being rare. Ordinary salts of zinc invariably contain small amounts of iron, which must be removed before they are used in the manufacture of colours. ”

“ Until the last quarter of a century, zinc was but little used, but of late it has taken the place for many useful purposes where lead was formerly used, principally owing to its cheapness and lightness. Zinc is a hard metal of a grayish colour, not easily bent but rather brittle, but when made nearly red hot, it is capable both of being rolled out into sheets and being beaten into form by the hammer. Zinc is about six-and-three-quarter times heavier than water. ”

“ Plates of platinum and pure or amalgamated zinc are separated by a porous pot, and each surrounded by some of the same solution of a salt of a metal more oxidizable than zinc, such as potassium. When the plates are connected together by means of a wire, no current flows, and no appreciable amount of zinc dissolves, for the dissolution of zinc would involve the separation of potassium and a gain in available energy. If sulphuric acid be added to the vessel containing the zinc, these conditions are unaltered and still no zinc is dissolved. ”

“ In zinc works zinc white is always made in the manner which has been described. It may also be obtained as a by-product in another metallurgical operation, the desilverisation of lead by Parkes’ process. In this process an alloy of silver and zinc is obtained. By sending a current of superheated steam over the molten alloy the zinc decomposes the steam, hydrogen and zinc oxide being formed. The zinc white is carried by the current of gas into chambers, in which it deposits. ”

“ Zinc is incapable of decomposing pure water; and if the zinc plates be kept moist with pure water, the galvanic pile does not act; but zinc is capable of oxidating itself when placed in contact with water, holding in solution either oxygen, atmospheric air, or nitrous or muriatic acid, &c.: and under such circumstances, the galvanic phenomena are produced, and their intensity is in proportion to the rapidity with which the zinc is oxidated. ”

“ Zinc dust contains both metals and their oxides, and methods which, from the volume of hydrogen generated, determine indirectly the percentage of metallic zinc do not give the real composition of the zinc dust. For the determination of the metallic components the material is digested with a solution of copper sulphate, which dissolves zinc and cadmium; the liquid is filtered, acidified, and decomposed with hydrogen sulphide, or treated with a solution of ammonium carbonate. ”

“ Later, when the whole apparatus has become warm, the zinc condenses to a liquid in the receiver, from which it is drawn off into molds. Commercial zinc often contains a number of impurities, especially carbon, arsenic, and iron.
Physical properties. Pure zinc is a rather heavy bluish-white metal with a high luster. It melts at about 420°, and if heated much above this temperature in the air takes fire and burns with a very bright bluish flame. ”

“ Zinc is not found in a native state. This ore is in the form of an oxide, as it is called. In roasting, certain of the impurities are driven off in gases, and mixing it with charcoal or coke and then applying heat to the confined mass, causes the zinc to melt and finally go off into a gas, as we shall presently see. ”

“ Zinc is not generally obtained from a particular ore of its own; but sublimes during the fusion of a mineral, or rather [Pg 118] a confused mass of minerals, that contains this semi-metal together with iron, copper, lead, sulphur, arsenic, and, like all other ores, an unmetallic earth.
Nevertheless, there is a substance which may be considered as the proper ore of zinc, because it contains a pretty large quantity of that semi-metal, a little iron, and an unmetallic earth. It is called Calamine, or Lapis Calaminaris ”

“ The method has since chiefly been applied to the treatment of copper ores and products, but has also been used for the recovery of nickel, gold, zinc, &c. The production of electrolytic zinc from solutions has been encouraged as a result of the shortage of pure zinc for war purposes, and several processes have been developed. In these processes the solution used consists either of zinc sulphate or of zinc chloride, the anodes consisting of metallic lead or of carbon, and the cathodes of pure zinc sheets. ”

“ As it is not easy to obtain zinc perfectly free from admixture of other metals, an artifice is commonly resorted to for obtaining a surface of pure metal, by rubbing a plate of the ordinary metal with quicksilver, which readily dissolves pure zinc, but is without action on the iron and other metals with which the zinc is contaminated, while the quicksilver is not acted upon by the diluted acid, but is merely the vehicle by which the pure zinc is presented to the liquid. ”

“ The Zinc adheres to the fore-part of the furnace preferably to any other, because that being the thinnest is therefore the coolest: and, in order further to promote its fixing on this part, they take care to keep the thin stone plates cool during the operation, by throwing water on them.
Hence it appears, that Zinc is not extracted from its ore by fusion and the precipitation of a Regulus, like other metallic substances. This is owing to the great volatility of our semi-metal, which cannot, without subliming, bear the degree of fire necessary to melt its ore. ”

“ When zinc containing indium is dissolved not quite completely in dilute sulphuric or muriatic acid, the whole of the indium originally present in the zinc is left in the black spongy or flocculent residue of undissolved metal, with which every one who has prepared hydrogen gas by means of zinc and acid is so well acquainted. Besides some zinc, this black residue is found to contain lead, cadmium, iron, and arsenic, less frequently copper and thallium, and in some cases, as that of the Freiberg zinc, a small proportion of indium. ”

“ With Zinc.—Add about 10 grams of granulated zinc; if the hydrogen comes off violently add water; if, on the other hand, the action is very slow, add sufficient dilute sulphuric acid to keep up a brisk effervescence. The reduction is hastened by warming, and is complete when the solution is quite colourless and a drop of the liquid tested with sulphocyanate of potassium gives no reaction for ferric iron. Filter through "glass wool" or quick filtering paper. The zinc should be still giving off gas rapidly, indicating a freely acid solution; if not, acid must be added. ”

“ A basic zinc yellow prepared from the sodium salt has a redder and more cloudy shade than one made from the potassium compound, but the difference is hardly noticeable when sodium-potassium chromate is employed.
Modern zinc yellows are invariably prepared from acid solutions, and consist of a double salt of zinc chromate and potassium bichromate, mixed with a varying amount of unchanged zinc oxide, which must not be regarded as an adulteration of the pigment, for its presence gives the substance “body.” ”

“ The presence of zinc in the ash of certain plants has been recognised for many years, especially in so far as the vegetation of soils containing much zinc is concerned. Risse, before 1865, stated that most plants when grown on such soils prove to contain greater or less quantities of zinc oxide. He states that the soil at Altenberg, near Aachen, is very rich in zinc, which rises as high as 20% in places. The flora of the soil is very diversified and zinc has been determined qualitatively in most and quantitatively in some of the plants. ”

“ The zinc, or which is the same thing, the spelter of the shops, should be melted in a vessel which exposes but a small surface to the action of the air, otherwise it would absorb oxygen so rapidly as to be converted into the flowers of zinc.—The melted metal should be poured as soon as possible into a mould of the proper size, made of stone or brass.—It is not necessary that the plates of copper should be more than one tenth of the thickness of those of zinc. ”

“ Some manganese is usually present replacing zinc. It is found in the zinc mines at Sterling Hill and Franklin Furnace in Sussex county, New Jersey, where it is associated with franklinite and willemite in crystalline limestone, and is mined as an ore of zinc. Artificial crystals of a white or yellowish colour are not infrequently formed by sublimation in zinc furnaces. ”