Harvey Washington Wiley

“ It is possible that potash salts, such as the chlorid, sulfate, and phosphate may be assimilated as such, but, as with other compounds, we must not deny to the plant the remarkable faculty of being able to decompose its most stable salts and to form from the fragments thus produced entirely new compounds. This is certainly true of the potash compounds existing in plants in combination with organic acids. The potash which is assimilated by plants exists in the soil chiefly in a mineral state, and that added as fertilizer is chiefly in the same condition. ”

“ On other soils of a sandy nature, or rich in calcium carbonate, such a fertilizer would have little value. The analyst in giving an opinion respecting the commercial value of a fertilizer, must be guided not only by the source of the material, its fineness or state of decomposition, and its general physical qualities, but also by the nature of the crop which it is to nourish and the kind of soil to which it is to be applied. ”

“ In every case the analyst may grow suspicious when he finds the content of nitrogen in a sample to fall below thirteen per cent. It must not be forgotten, however, that some potassium nitrate may be present in the sample, and since that salt contains only 13.87 per cent of nitrogen its presence would tend to lower the value of the fertilizer; but although the potash itself is a fertilizer of value it is not worth more than one-third as much as nitrogen. In all cases of suspected adulteration, it is advisable to make a complete analysis. ”

“ An ammoniacal salt is only partly changed to a state suited to plant nutrition while organic nitrogen is forced to undergo a complete transformation before it becomes available to supply the needs of the growing plant. It is important, therefore, equally to the analyst, the merchant, and the agronomist, to know definitely the forms of combination in which the nitrogen exists and the relative proportion of the different combinations. ”

“ The nascent hydrogen which unites with the nascent nitrogen during the combustion is also derived from the organic matter which always contains enough carbon to decompose the water formed in order to be oxidized to carbon dioxid. While at first, therefore, during combustion, the hydrogen may unite with the oxygen, it becomes again free by the oxidation of the carbon and in this condition unites with the nascent nitrogen to form ammonia. ”

“ Not only does the acetic acid fail to prevent the precipitation of some of the lime, but it also dissolves more or less of the iron and aluminum phosphates. The solution of the precipitate and its reprecipitation by the addition of ammonia, may free the second precipitate from lime, but it increases the error due to the solubility of the aluminum salt. The methods recently introduced for the estimation of iron and alumina in presence of excess of lime and phosphoric acid are not entirely satisfactory, but are the best which can now be offered. ”

“ Land treated generally with wood-ashes becomes more amenable to culture, is readily kept in good tilth, and thus retains moisture in dry seasons and permits of easy drainage in wet. These effects are probably due to the lime content of the ash, a property moreover favorable to nitrification and adapted to correcting acidity. Injurious iron salts, which are sometimes found in wet and sour lands, are precipitated by the ash and rendered innocuous or even beneficial. A good wood-ash fertilizer therefore is worth more than would be indicated by its commercial value calculated in the usual way. ”

“ Continuous solution of soils beneath the sea gives rise to the formation of great lakes of saturated water, in which occurs the development of much marine vegetation. On the evaporation of this water, due to geologic isolation, the decomposition of nitrogenous organic matter causes generation of nitric acid, which, coming in contact with the calcareous rocks, attacks them, forming calcium nitrate, which, in presence of sodium sulfate, gives rise to a double decomposition into sodium nitrate and calcium sulfate. ”

“ Even the phosphorus and sulfur which after ignition appear as phosphates and sulfates, have previous thereto existed in an organic form to a large extent. The silica itself is profoundly modified in the organism of the growing plant and doubtless does not exist there in the purely mineral form in which it is found in the ash. During the progress of incineration, with proper precautions, all the phosphorus and sulfur are oxidized and appear as phosphoric and sulfuric acids. The silica is reduced to a mineral state, and if a high heat be employed silicates are formed. ”

“ Availability of Phosphatic Fertilizers.—There is perhaps no one question more frequently put to analysts by practical farmers than the one relating to the availability of fertilizing materials. The object of the manufacturer should be to secure each of the valuable ingredients of his goods in the most useful form. The ideal form in which phosphoric acid should come to the soil is one soluble in water. ”

“ At present, the only conclusion that can be safely drawn from the work, is that it would be unsafe to make any generalization upon the subject until more facts are at hand, except that the present methods are unscientific and, unsatisfactory. As the work progresses, new features present themselves, and in such a way as to show that they must be given careful consideration before drawing any final conclusions in the matter. ”

“ In the distillation it is a common practice, especially in Germany, to do away with the condensing worm and to carry a long glass tube from the distilling flask directly into the acid on the receiver. The only inconvenience in this method is the heating of the contents of the receiving flask, but this is attended with no danger of loss of ammonia and the distillate, on account of the high temperature it acquires, is left free of carbon dioxid. Many of these minor changes have tended to simplify the process, but without affecting the principle of the method in the least. ”

“ The sulfur trioxid set free acts upon the organic matter in the powerful manner peculiar to it, and the potassium sulfate formed in the last reaction above unites with another molecule of sulfuric acid, and the same round of reactions is repeated continuously so long as there is an excess of free sulfuric acid present in the mixture. As the liquid becomes more concentrated with the continuation of the digestion, the boiling-point increases so that the effect is the same as heating under pressure. ”

“ Arbitrary Determination of Reverted Phosphoric Acid.—The so-called reverted phosphoric acid, that is, the acid insoluble in water and soluble in a solution of ammonium citrate, is the most difficult constituent of commercial fertilizers from the point of view of the scientific analyst. A review of all the standard methods which have been given in the preceding pages for its determination must convince every careful observer that, as a rule, each process is based on arbitrary standards, and can give only concordant results when carried out under strictly unvarying conditions. ”

“ The Application of Chile Saltpeter to the Soil.—The analyst is often asked to determine the desirability of the use of sodium nitrate as a fertilizer and the methods and times of applying it. These are questions which are scarcely germane to the purpose of this work but which, nevertheless, for the sake of convenience may be briefly discussed. In the first place it may be said that the data of a chance chemical analysis will not afford a sufficiently broad basis for an answer. A given soil may be very rich in nitrogen as revealed by chemical analysis, and yet poor in an available supply. ”

“ Classification.—Nitrogen, phosphoric acid, and potash are the most important of the plant foods both from a commercial and physiological point of view. They are the chief constituents of the most important fertilizers and manures, but are by no means the sole essential elements of plant nutrition. Lime, magnesia, soda, sulfur, chlorin, and many other elements are found constantly in plants and must be regarded as normal constituents thereof. ”

“ Verification of the Strength of the Standard Solution of Phosphoric Acid.—The strength of the standard solution of phosphoric acid is verified by evaporating a known volume, fifty cubic centimeters for example, with a solution of ferric hydroxid containing a known quantity of ferric oxid. The mass having been evaporated to dryness, and ignited in a platinum crucible, gives an increase in the weight of the iron oxid exactly equal to the amount of anhydrous phosphoric acid contained therein, both the nitric acid and ammonia being driven off by the heat. ”

“ Since all organic substances of whatever kind are dissolved by the boiling acid the previous pulverization of the material need be carried only far enough to secure a fair sample. Many substances give up practically all their nitrogen as ammonium sulfate when heated with sulfuric acid as, for instance, urea, asparagin, and the glutens. ”

“ When once the nitric acid has been absorbed by the living rootlet it is held with great tenacity. Living plants macerated in water give up only a trace of nitric acid, but if they be previously killed with chloroform the nitric acid they contain is easily leached out.
The molecule of sodium nitrate is decomposed in the process of the absorption of the nitric acid. The acid enters the plant organism and the soda is excreted and left to combine with the soil acids. The nascent soda may thus play a role of some importance in decomposing particles of minerals containing potash or phosphoric acid. ”