Summary

Portrait of Joseph John Thomson Joseph John Thomson Rays of Positive Electricity and Their Application to Chemical Analyses… (1913)

If the corpuscles which neutralize the positive particles are not free but are in the molecules of the gas through which these particles are passing, we can understand why there is a lower as well as an upper limit to the velocity of the particles which give rise to the secondaries due to particles which have been neutralized while passing through the electric and magnetic fields. For on this view the particle before it can be neutralized has to detach a corpuscle from an atom or molecule.
Source: Wikisource

Portrait of Joseph John Thomson Joseph John Thomson Rays of Positive Electricity and Their Application to Chemical Analyses… (1913)

If it required the same energy to ionize an atom of oxygen as one of hydrogen, V would be the same for oxygen as for hydrogen. To give an atom of oxygen this velocity would require a potential difference of 16 x 20,000, or 320,000 volts, a much greater potential difference than we usually apply to the discharge tubes. Thus we see that we cannot expect any except the lighter gases such as hydrogen or helium to show secondaries of the type we are considering.
Source: Wikisource

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