Summary

Portrait of Joseph John Thomson Joseph John Thomson Rays of Positive Electricity and Their Application to Chemical Analyses… (1913)

Again the method of the positive rays enables us when we have found the substance to say whether the molecule is monatomic or diatomic; if it is diatomic we shall have two new parabolas, one indicating particles with a mass twice that of the picartles producing the other; if the molecule is monatomic there will be only one parabola unless the particle acquire a double charge and the presence of this extra charge can be recognized by the tests previously described.
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Portrait of Joseph John Thomson Joseph John Thomson Rays of Positive Electricity and Their Application to Chemical Analyses… (1913)

Let us now consider the photograph taken with the lighter constituents (Fig. 48, Plate IV.) : here we find the line corresponding to helium; to neon, this is very strong and there is also a line corresponding to the neon atom with a double charge; to argon, and in addition there is a line corresponding to an element with an atomic weight 22. A molecule of carbonic acid with a double charge would give a line in this position, but this cannot be the origin of the line as the carbonic acid can be removed from the gas without producing any change in the brightness of the line.
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Portrait of Joseph John Thomson Joseph John Thomson Rays of Positive Electricity and Their Application to Chemical Analyses… (1913)

As these particles are the atoms and molecules of the gases in the discharge tube it is evident that in this way we can determine the atomic or molecular weight of the gases in the positive rays. We can thus identify these gases as far as can be done by the knowledge of their atomic weight. The study of the photographs gives us in fact the atomic weights of the various gases in the tube and thus enables us to determine the nature of the contents of the tube. We can thus analyse a gas by putting a small quantity of it into a discharge tube and taking a photograph of the positive rays.
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