Combustion gas

“ When the flame is suffered to rise beyond the standard height, the combustion of the gas becomes imperfect, part of the gas passes through the flame unburnt, and occasions the source of the offensive odour alluded to, which the gas lights never produce when the combustion of the gas is complete. ”

“ When the fire burns bright, much radiant heat will be sent off from it; but when [150] it is smothered up, very little will be generated: most of the heat produced will then be expended in giving elasticity to a thick dense vapour, or smoke, which is seen rising from the fire; and the combustion being very incomplete, the carburetted hidrogen gas of the coal being driven up the chimney without being inflamed, the fuel is wasted to little purpose. ”

“ Since the radiation losses of a burning fuel are proportional to the time required for burning, it is evident that the rate of combustion has much to do with the efficient development of the heat contained in it, and it is true that rapid combustion develops more useful heat from a given fuel than slow. ”

“ In the case of a steam-boiler the energy of combustion is transmitted to water inside an air-tight vessel. The fuel does not actually touch the "working fluid." In the gas or oil engine the fuel is brought into contact and mixed with the working fluid, which is air. It combines suddenly with it in the cylinder, and heat energy is developed so rapidly that the act is called an explosion. Coal gas, mineral oils, alcohol, petrol, etc., all contain hydrogen and carbon. If air, which contributes oxygen, be added to any of these in due proportion, the mixture becomes highly explosive. ”

“ Strictly speaking, much, and sometimes even most, of the heating effected by solid or liquid fuel is actually performed by the gases given off during the combustion. We speak, however, of gaseous fuel only in those cases where we supply a combustible gas from the outset, or where we produce from ordinary solid (or liquid) fuel in one place a stream of combustible gas which is burned in another place, more or less distant from that where it has been generated. ”

“ A second entirely independent mode of propagation of the combustion lies at the basis of the phenomenon that an explosive gas-mixture can be ignited by strong compression or—more correctly—by the rise of temperature thereby produced. The increase of the concentrations of the reacting substances consequent upon this increase of pressure raises the reaction-velocity in accordance with the law of chemical mass-action, and so enormously favours the rapid evolution of the heat of combustion. ”

“ That which under these conditions comes from the coal beneath, when gradually heated by the fire above, is combustible gas, and this gas is burned as it passes through the fire. In this case the formation or non-formation of smoke depends mainly on how this gas is burned, whether completely or incompletely. If the air supplied for its combustion is insufficient, smoke will be formed as it is when we turn up an Argand gas-flame so high that the gas is too great in proportion to the quantity of air that can enter the glass chimney. ”

“ Should the air be in excess of that required for complete combustion, or should a great quantity of incombustible gas, such as nitrogen be present in the mixture, the fuel will be completely burned, but the speed of burning will be reduced owing to the dilution. ”

“ The quantities of heat and light produced by the combustion of inflammable gases are by no means in the same constant relation to each other; one frequently increases, whilst the other diminishes; and this is eminently the case when coal gas and oil gas are burned against each other. The quantity of heat liberated is, speaking generally, as the quantity of gas consumed, and this is greatest with the coal gas; but the quantity of light is nearly as the quantity of carbon that is well burnt in the flame, and this is greatest in the oil gas. ”

“ We are now in a position to form the following picture of the processes which follow upon the ignition of a combustible gas-mixture contained in a long tube. First we have the condition of slow combustion; the heat is conveyed by conduction to the adjacent layers, and there follows a velocity of propagation of a few metres per second. But since the combustion is accompanied by a high increase of pressure, the adjacent, still unburnt layers are simultaneously compressed, whereby the reaction-velocity increases, and the ignition proceeds faster. ”

“ When the supply of air is sufficient for the immediate and complete combustion of the whole of the combustible matter, no such precipitation takes place, and the flame is neither white nor brilliant. The richest coal-gas, mixed with sufficient air to convert all its hydrogen and carbon into water and carbonic acid, explodes with a pale blue flash; yet the same gas, when consumed in the ordinary way, burns with a rich white flame. Every one must have noticed the effect of a gust of wind upon the flaring gas-jets of a butcher’s shop ”

“ If seven bulbfuls of air be mixed with one bulbful of gas, an explosive mixture of 1 to 7 is produced, this being 294 the proportion commonly employed for street-gas. For producer-gases the preferred proportion is 1 to 1, oxygen being often added to the air in order to insure complete combustion. ”

“ Oxygen gas will not burn of itself, but it aids the decomposition by fire of bodies that are combustible. It is therefore called a supporter of combustion. But hydrogen gas, though it burns of itself [Pg 35] will extinguish a flame immersed in it. It is therefore said to be a body which will burn, but will not support combustion.
"As coals are to burning coals, and wood to fire; so is a contentious man to kindle strife."—Proverbs xxvi.
46. What becomes of the nitrogen that is inhaled with the air? ”

“ A wide range of fuels may be used in an internal-combustion engine. They may be either gaseous, liquid, or even solid. In stationary engines hydrogen, coal gas, natural gas, blast-furnace gas, and [156] producer gas are employed to advantage. Volatile fuels, such as alcohol, bensol, gasoline, and kerosene, are turned into a mist or vapor and then burned as a gas. In engines of the Diesel type any liquid fuel ranging down to thick crude oils may be employed, and in one type of engine, which, however, has not proved commercially practicable, coal dust is burned in the cylinder. ”

“ I wish upon the present occasion to make merely a sort of general statement of what I conceive to be combustion, and what I conceive to be a boiler, and then to try to make a useful application of these ideas to the locomotive.
Treating first the subject of combustion, let us take the top of the grate-bars as our starting point. When we shovel coal upon the grate bars and ignite it, what happens first? We separate the two constituents of coal, the carbon from the hydrogen. We make a gas works. Carbon by itself will burn no more than a stone; neither will hydrogen. ”

“ As the air is increased beyond the proper proportions the explosions become weaker and weaker as the gas becomes leaner until the engine stops entirely. Because of the fact that it is impossible in practice to so thoroughly mix the gas and air that each particle of gas is in contact with a particle of air, the volume of air used for the combustion is much greater than that theoretically required. A SLIGHT excess of air, making a lean mixture, increases the efficiency of combustion although it reduces the temperature and pressure attained in the cylinder. ”

“ The oxygen of the combustion only forms one-fifth of the total volume of air; therefore, if we were to supply pure oxygen in place of air, and in equal volume, the action would be several times as intense. If the oxygen is mixed with the fuel gas in the proportion that burns to the very best advantage, the flame is still further strengthened and still more heat is developed because of the perfect combustion. The greater the amount of fuel gas that can be burned in a certain space and within a certain time, the more heat will be developed from that fuel. ”

“ The phenomenon called combustion by which we obtain the heat energy necessary for the operation of the internal combustion engine is a chemical combination of the air with the fuel. This process results in heat and some light which is equal in quantity to the energy required to separate the fuel compound into its elements or to build it up in its present form from the original elements. If the process is comparatively slow, the compound is called a fuel, if it is instantaneous it is called an explosive. ”

“ A gas flame is gas in a state of combustion, whereas the electric light is no example of it, although the wire within the glassen cylinder is red hot, and to all appearance burning. Combustion generally takes place through the strong affinity of some element, such as carbon in a substance for the oxygen in the atmosphere. In coal gas, for instance, the carbon contained in it unites with the oxygen in the air to form a colorless substance called carbonic acid gas. ”

“ For the best results the gas must be completely ignited at the point of maximum compression, and the pressure must be established on the dead center, so that the indicator card will show a straight and vertical combustion line. As all gases require a certain length of time in which to burn, the ignition should have LEAD, that is, should be started before the end of the stroke so that combustion will be complete at dead center. The amount of ignition lead required depends on the fuel and the compression. ”

“ The art of purifying coal gas, has at length however, been carried to such a perfection, that every possibility of a disagreeable odour arising from its combustion has been wholly removed, in all cases where attention is paid to the perfect combustion of the gas, by keeping the flame of the same of a proper magnitude. ”

“ The same occurs when the temperature of any portion of the hydrogen is reduced below that intensity required for the combustion of the newly separated charcoal. Solid bodies, as tallow, oils, and fats, which burn with flame, are converted into the state of gas by the heat required to kindle them, and it is this gaseous matter which suffers combustion, and not the substance which produces it. ”

“ As the working medium in an internal combustion engine is in direct contact with the fuel it must not only be uninflammable 13but it must also be capable of sustaining combustion and must have a great expansion for a given temperature range. ”

“ A very similar thing happens at each explosion of an internal combustion engine. Into the cylinder is drawn a charge of gas, containing carbon, oxygen, and hydrogen, and also a proportion of air. This charge is squeezed by the inward movement of the piston; its temperature is raised by the compression, and at the proper moment it is ignited. The oxygen and carbon seize on one another and burn (or combine) , the heat being increased by the combustion of the hydrogen. The air atoms are expanded by the heat, and work is done on the piston. ”

“ The fuel is fed into the top of such a furnace, and either by raking or by shaking it descends occasionally, stage by stage, till it arrives at the bottom, where it is utterly inorganic and mere refuse. A beautiful earthworm economy of the last dregs of combustible matter in any kind of refuse can thus be attained. Such methods of combustion as this, though valuable, are plainly of limited application; but for the great bulk of fuel consumption some gas-making process must be looked to. No crude combustion of solid fuel can give ultimate perfection. ”

“ If a drop of gasoline, in one case is broken up into five hundred tiny particles, and in the other case into one thousand, it is obvious that in the latter case the air comes into contact with double the surface of the liquid than in the former case, hence will be so much more efficient, for the following reason:
Perfect combustion is the desired object in the engine cylinder. The more nearly the vapor approaches (121) an impalpable gas the quicker will it ignite. Furthermore, the more intimate the air and the vapor are mixed the better will be the explosion or combustion. ”

“ Yet it is one whose form can be changed, and whose hardness can be completely destroyed, by the simple process of combustion. It can be deprived of its high lustre, and of its power of breaking up by refraction the light of the sun into the various tints of the solar spectrum, simply by heating it to a red heat, and then plunging it into a jar of oxygen gas. It immediately expands, changes into a coky mass, and burns away. The product left behind is a mixture of carbon and oxygen, in the proportions in which it is met with in carbonic-anhydride, or, carbonic acid gas deprived of its water. ”

“ The combustion, when once begun, continues for a considerable time, but weakens gradually, in proportion as the quantity of azotic gas remaining from the combustion increases, till at last the azotic gas is in such over proportion that the combustion can no longer be supported, and the flame goes out. ”

“ Another difference between the actual and theoretical results obtained is that due the perfect combustion in the calorimeter and the imperfect combustion in the engine. Since some gases require more air for their combustion than others, less of the first gas will be taken into the cylinder on a charge than the latter, which tends still further to balance the heating effect of rich and lean gases in the cylinder. ”