Josiah Willard Gibbs,
Scientific Papers of Josiah Willard Gibbs
(1906)
“ To ascertain the nature of the derived surface and its relations to the primitive surface sufficiently to construct it when the latter is given, it is only necessary to use the principle that the volume, entropy, and energy of the whole body are equal to the sums of the volumes, entropyes, and energies respectively of the parts, while the pressure and temperature of the whole are the same as those of each of the parts. Let us commence with the case in which the body is in part solid, in part liquid, and in part vapor. ”
