Michael Faraday

“ All the facts show us that that power commonly called chemical affinity, can be communicated to a distance through the metals and certain forms of carbon; that the electric current is only another form of the forces of chemical affinity; that its power is in proportion to the chemical affinities producing it; that when it is deficient in force it may be helped by calling in chemical aid, the want in the former being made up by an equivalent of the latter; that, in other words, the forces termed chemical affinity and electricity are one and the same. ”

“ In a current, whatever form the discharge may take, or whatever part of the circuit or current is referred to, as much positive force as is there exerted in one direction, so much negative force is there exerted in the other. If it were not so we should have bodies electrified not merely positive and negative, but on occasions in a most extraordinary manner, one being charged with five, ten, or twenty times as much of both positive and negative electricity in equal quantities as another. ”

“ There is every reason to believe that the magnet or magnetic needle will become an excellent measurer of the conducting power of substances rotated near it; for I have found by careful experiment, that when a constant current of electricity was sent successively through a series of wires of copper, platina, zinc, silver, lead, and tin, drawn to the same diameter; the deflection of the needle was exactly equal by them all. It must be remembered that when bodies are rotated in a horizontal plane, the magnetism of the earth is active upon them. ”

“ Electric discharges in the atmosphere in the form of balls of fire have occasionally been described. Such phenomena appear to me to be incompatible with all that we know of electricity and its modes of discharge. As time is an element in the effect (1418. 1436.) it is possible perhaps that an electric discharge might really pass as a ball from place to place; but as every thing shows that its velocity must be almost infinite, and the time of its duration exceedingly small, it is impossible that the eye should perceive it as anything else than a line of light. ”

“ It would seem strange, if a theory which refers all the phenomena of insulation and conduction, i.e. all electrical phenomena, to the action of contiguous particles, were to omit to notice the assumed possible case of a vacuum. Admitting that a vacuum can be produced, it would be a very curious matter indeed to know what its relation to electrical phenomena would be; and as shell-lac and metal are directly opposed to each other, whether a vacuum would be opposed to them both, and allow neither of induction or conduction across it. Mr. Morgan299 has said that a vacuum does not conduct. ”

“ Sometimes when the negative ball was large, the machine in powerful action, and the rarefaction high, the ball would be covered over half its surface with glow, and then, upon a hasty observation, would seem to exhibit no dark space: but this was a deception, arising from the overlapping of the convex termination of the negative glow and the concave termination of the positive stream. More careful observation and experiment have convinced me, that when the negative glow occurs, it never visibly touches the luminous part of the positive discharge, but that the dark space is always there. ”

“ It rivals in brilliancy, if it does not even very much surpass, the light from the discharge of voltaic electricity; but it endures for an instant only, and is attended by a sharp noise like that of a small explosion. Still no difficulty can arise in recognising it to be the same spark as that from the voltaic battery, especially under certain circumstances. The eye cannot distinguish the difference between a voltaic and a common electricity spark, if they be taken between amalgamated surfaces of metal, at intervals only, and through the same distance of air. ”

“ A pure strong solution of ammonia is as bad a conductor, and therefore as little liable to electrolyzation, as pure water; but when sulphate of ammonia is dissolved in it, the whole becomes a conductor; nitrogen almost and occasionally quite pure is evolved at the anode, and hydrogen at the cathode; the ratio of the volume of the former to that of the latter varying, but being as 1 to about 3 or 4. This result would seem at first to imply that the electric current had decomposed ammonia, and that the nitrogen had been determined towards the positive electrode. ”

“ But the diminution of power to one-half on the side of the gaseous body towards the metal is only a slight result of what seems to me to flow as a necessary consequence of the known constitution of gases. An atmosphere of one gas or vapour, however dense or compressed, is in effect as a vacuum to another: thus, if a little water were put into a vessel containing a dry gas, as air, of the pressure of one hundred atmospheres, as much vapour of the water would rise as if it were in a perfect vacuum. ”

“ Upon considering the effects of terrestrial magneto-electric induction which have now been described, it is almost impossible to resist the impression that similar effects, but infinitely greater in force, may be produced by the action of the globe, as a magnet, upon its own mass, in consequence of its diurnal rotation. It would seem that if a bar of metal be laid in these latitudes on the surface of the earth parallel to the magnetic meridian, a current of electricity tends to pass through it from south to north, in consequence of the travelling of the bar from west to east (172.) ”

“ As far as experiment has proceeded, it appears, therefore, impossible either to evolve or make disappear one electric force without equal and corresponding change in the other. It is also equally impossible experimentally to charge a portion of matter with one electric force independently of the other. Charge always implies induction, for it can in no instance be effected without; and also the presence of the two forms of power, equally at the moment of the development and afterwards. There is no absolute charge of matter with one fluid; no latency of a single electricity. ”

“ It is a striking thing to observe the revolving copper plate become thus a new electrical machine; and curious results arise on comparing it with the common machine. In the one, the plate is of the best non-conducting substance that can be applied; in the other, it is the most perfect conductor: in the one, insulation is essential; in the other, it is fatal. In comparison of the quantities of electricity produced, the metal machine does not at all fall below the glass one; for it can produce a constant current capable of deflecting the galvanometer needle, whereas the latter cannot. ”

“ Or, if we adopt the atomic theory or phraseology, then the atoms of bodies which are equivalents to each other in their ordinary chemical action, have equal quantities of electricity naturally associated with them. But I must confess I am jealous of the term atom; for though it is very easy to talk of atoms, it is very difficult to form a clear idea of their nature, especially when compound bodies are under consideration. ”

“ But admitting that chemical action is the source of electricity, what an infinitely small fraction of that which is active do we obtain and employ in our voltaic batteries! Zinc and platina wires, one-eighteenth of an inch in diameter and about half an inch long, dipped into dilute sulphuric acid, so weak that it is not sensibly sour to the tongue, or scarcely to our most delicate test-papers, will evolve more electricity in one-twentieth of a minute (860.) than any man would willingly allow to pass through his body at once. ”

“ When the brush discharge is observed in air at the positive and negative surfaces, there is a very remarkable difference, the true and full comprehension of which would, no doubt, be of the utmost importance to the physics of electricity ”

“ Even when the water is not present in large quantity, but is merely that of combination, still secondary results often ensue: for instance, it is very possible that in Sir Humphry Davy's decomposition of the hydrates of potassa and soda, a part of the potassium produced was the result of a secondary action. Hence, also, a frequent cause for the disappearance of the oxygen and hydrogen which would otherwise be evolved: and when hydrogen does not appear at the cathode in an aqueous solution, it perhaps always indicates that a secondary action has taken place there. ”

“ No other known power has like direction with that exerted between an electric current and a magnetic pole; it is tangential, while all other forces, acting at a distance, are direct. Hence, if a magnetic pole on one side of a revolving plate follow its course by reason of its obedience to the tangential force exerted upon it by the very current of electricity which it has itself caused, a similar pole on the opposite side of the plate should immediately set it free from this force; for the currents which tend to be formed by the action of the two poles are in opposite directions ”

“ Looking forward to such a table as of extreme utility (if well-constructed) in developing the intimate relation of ordinary chemical affinity to electrical actions, and identifying the two, not to the imagination merely, but to the conviction of the senses and a sound judgement, I may be allowed to express a hope, that the endeavour will always be to make it a table of real, and not hypothetical, electro-chemical equivalents; for we shall else overrun the facts, and lose all sight and consciousness of the knowledge lying directly in our path. ”

“ It is the opinion of several philosophers, that the presence of water is essential in electro-chemical decomposition, and also for the evolution of electricity in the voltaic battery itself. As the decomposing cell is merely one of the cells of the battery, into which particular substances are introduced for the purpose of experiment, it is probable that what is an essential condition in the one case is more or less so in the other. ”

“ If we endeavour to consider electricity and magnetism as the results of two forces of a physical agent, or a peculiar condition of matter, exerted in determinate directions perpendicular to each other, then, it appears to me, that we must consider these two states or forces as convertible into each other in a greater or smaller degree ”

“ Under these circumstances, there is an opposition of forces: the fluid, which brings into play the stronger set of chemical affinities for the zinc, (being the dilute acid,) overcomes the force of the other, and determines the formation and direction of the electric current; not merely making that current pass through the weaker liquid, but actually reversing the tendency which the elements of the latter have in relation to the zinc and platina if not thus counteracted, and forcing them in the contrary direction to that they are inclined to follow, that its own current may have free course. ”

“ An electrolyte is always a compound body: it can conduct, but only whilst decomposing. Its conduction depends upon its decomposition and the transmission of its particles in directions parallel to the current; and so intimate is this connexion, that if their transition be stopped, the current is stopped also; if their course be changed, its course and direction change with them; if they proceed in one direction, it has no power to proceed in any other than a direction invariably dependent on them. ”

“ The rounded end of a brass rod, 0.3 of an inch in diameter, was covered with a positive glow by the working of an electrical machine: on stopping the machine, so that the charge of the connected conductor should fall, the glow changed for a moment into brushes just before the discharge ceased altogether, illustrating the necessity for a certain high continuous charge, for a certain sized termination. Working the machine so that the intensity should be just low enough to give continual brushes from the end in free air, the approach of a fine point changed these brushes into a glow. ”

“ It was in attempts to prove the existence of electricity separate from matter, by giving an independent charge of either positive or negative power only, to some one substance, and the utter failure of all such attempts, whatever substance was used or whatever means of exciting or evolving electricity were employed, that first drove me to look upon induction as an action of the particles of matter, each having both forces developed in it in exactly equal amount. ”

“ It will often happen that the electrodes used may be of such a nature as, with the fluid in which they are immersed, to produce an electric current, either according with or opposing that of the voltaic arrangement used, and in this way, or by direct chemical action, may sadly disturb the results. Still, in the midst of all these confusing effects, the electric current, which actually passes in any direction through the body suffering decomposition, will produce its own definite electrolytic action. ”

“ If in any case of electro-decomposition we consider the decomposing body as placed so that the current passing through it shall be in the same direction, and parallel to that supposed to exist in the earth, then the surfaces at which the electricity is passing into and out of the substance would have an invariable reference, and exhibit constantly the same relations of powers. ”

“ When mercury constitutes one or both of the surfaces used, the brightness of the spark is greatly increased. But as this effect is due to the action on, and probable combustion of, the metal, such sparks must only be compared with other sparks also taken from mercurial surfaces, and not with such as may be taken, for instance, between surfaces of platina or gold, for then the appearances are far less bright, though the same quantity of electricity be passed. It is not at all unlikely that the commonly occurring circumstance of combustion may affect even the duration of the light ”