Josiah Willard Gibbs,
Scientific Papers of Josiah Willard Gibbs
(1906)
“ When the body consists of a compound of two different homogeneous states, the point which represents the compound state will be at the center of gravity of masses proportioned to the masses of the parts of the body in the two different states and placed at the points of the primitive surface which represent these two states (i.e., which represent the volume, entropy, and energy of the body, if its whole mass were supposed succesively in the two homogeneous states which occur in its parts.) ”
