Clay model

“ If the transporting stream flows through valleys whose sides are formed of limestone, chalk, sandstone or other materials, these will become mixed with the clay, and to so great an extent has the mixing occurred that very few clays occur in a state even approximating to purity. The majority of clays are contaminated with iron oxide, lime compounds and free silica in such a fine state of division that it is impossible to purify them completely without [50] destroying the nature of the clay. ”

“ The extent to which a clay can thus bind other materials together into a plastic mass depends, apparently, on the plasticity of the clay itself and on the size and nature of the particles of the added material; the more plastic the clay the larger will be the amount of material it can thus 'bind,' and the finer the latter the more easily will it form a strong material when mixed with a plastic clay. ”

“ If, however, the temperature is raised to about 500° C. a decomposition of the material commences and water [154] is evolved. This water—which is commonly termed 'combined water'—is apparently an essential part of the clay-molecule and when once it has been removed the most important characteristics of the clay are destroyed and cannot be restored. The reactions which occur when clay is heated are complex and are rendered still more difficult to study by the apparent polymerization of the alumina formed. ”

“ The effect of adding water to a dry clay is curious. At first the particles in contact with the water become sticky and plastic, and if the proportion of water added is suitable and the mixing is sufficiently thorough a plastic mass will be produced, the characteristics of which will depend on the nature of the clay used. This process of mixing clay with a limited amount of water is known as 'tempering.' The proportion of water required to make a paste of suitable consistency for modelling appears to be constant for each clay. ”

“ If the Challenger hypothesis, that the red clay is the residue left by dissolved Foraminiferous skeletons, is correct, then all these deposits alike would be directly, or indirectly, the product of living organisms. But just as a silicious deposit may be metamorphosed into opal or quartzite, and chalk into marble, so known metamorphic agencies may metamorphose clay into schist, clay-slate, slate, gneiss, or even granite. ”

“ Glacially deposited clays are characterised by their heterogeneous composition, some of them containing far more sand than true clay, whilst yet retaining a sufficient amount of plasticity to enable them to be used for rendering embankments impervious and for the manufacture of common bricks, and, occasionally, of coarse pottery; others contain so much sand as to be useless for these purposes. Most glacial deposits contain a considerable proportion of stones and gravel which must be removed before the clay can be used. ”

“ But if we investigate different mountain chains, we find gneiss, mica-schist, hornblende-schist, chlorite-schist, hypogene limestone, and other rocks, succeeding each other, and alternating with each other in every possible order. It is, indeed, more common to meet with some variety of clay-slate forming the uppermost member of a metamorphic series than any other rock; but this fact by no means implies, as some have imagined, that all clay-slates were formed at the close of an imaginary period when the deposition of the crystalline strata gave way to that of ordinary sedimentary deposits. ”

“ In regard to the wares made from clays retaining the colors produced by the elements which they contain, in a natural state, it may be said that the amount of heat necessary for proper firing, decreases with the depth of color. This rule, although it may accurately indicate the temperature at which any given clay should be fired, is simply artificial, except in so far as the depth of color shows the presence of an amount of foreign matter, which by its action increases the fusibility of the clay. ”

“ Primary clays, on the contrary, have been derived from rocks which have undergone chemical decomposition, one of the products being clay. The most important primary clays are the kaolins, which are derived from the decomposition of felspar, but other primary clays derived from other minerals are known, though less frequently mentioned. ”

“ A plastic substance is one with the characteristics of 'a fluid of so great a viscosity that it does not lose its shape under the influence of gravitation.'
The causes of plasticity appear to be somewhat numerous, though there is no generally accepted explanation of this remarkable quality which distinguishes clays from most other substances. It is true that wet sand, soap, wax, lead and some other materials possess a certain amount of plasticity, but not to anything like the same extent as clay. ”

“ The material which passes through the finest sieve employed will contain all the true clay in the material; that is to say, the coarser portion will, as already mentioned, be devoid of the ordinary characteristics of clay. At the same time, this very fine material will seldom consist exclusively of clay, but will usually contain a considerable proportion of silt, extremely fine mineral particles and, in the case of calcareous clays, a notable proportion of calcium carbonate in the form of chalk or limestone particles. ”

“ Also by weighing, an idea of the amount of sand may be imagined; the more sand there is in clay the lighter it will be, all other conditions being identical. A comparison between two clays will enable some opinion to be formed of their relative stability in earthwork, though, of course, there are many other features to be considered. All impure clays, such as shaly clay, sandy clay, loamy clay, and marly clay require to be carefully treated, although they may be easier to manage than yellow or brown clay. ”

“ The relative proportions of the colloidal material and the sizes of the non-plastic grains will exercise an important influence on all the physical characteristics mentioned above, and therefore on the plasticity.
The manner in which slightly plastic clays become highly plastic in nature is by no means certainly known. It has long been understood that the increase of plasticity is due to changes undergone by the clay during transportation. ”

“ As soil acids break down silts, the less-soluble portions recombine into clay crystals. Clay particles are much smaller than silt grains. It takes an electron microscope to see the flat, layered structures of clay molecules. Shales and slates are rocks formed by heating and compressing clay. Their layered fracture planes mimic the molecules from which they were made. Pure clay is heavy, airless and a very poor medium for plant growth. ”

“ It would thus appear that no process of mechanical separation will serve for a complete purification of a clay; indeed, there are good reasons for supposing that extremely fine particles of quartz and mica render physical characteristics an uncertain means of accurately distinguishing clays from other rock dust.
When chemical methods of investigation are employed the problem is not materially altered, nor is its solution fully attained. ”

“ At a gentle heat, the clay is dried and retains most of its power of becoming plastic when moistened; very little, if any, decomposition occurs. At a higher temperature it loses its 'combined water,' the clay molecule apparently dissociating, and a hard stony mass—consisting of particles of free silica and free alumina cemented together by the more easily fusible impurities present—is formed. ”

“ Ever since the publication of Seger's memorable [148] papers (7) , and to a small extent before that time, it has been generally understood that china clay or kaolin represented the true essential constituent of clays, but several investigators have been so imbued with the idea that all true clay substance must have a crystalline form that they have frequently used the term 'kaolinite' to include the 'amorphous' substance in plastic clays. ”

“ The freezing of the water breaks down the larger lumps of clay, by the resulting expansion, and this facilitates the subsequent levigation, the cohesion between the particles being destroyed.
If the clay contains larger proportions of lime or115 magnesia, a little experience will enable their presence to be detected at once by the way the clay behaves on being placed in contact with water. Pure clay quickly forms a fatty and extremely plastic paste, and sticks closely to the tongue when applied in the dry state. ”

“ Mellor and Holdcroft point out that there is no critical point of decomposition for clay substance obtained from china clay, as it appears to lose water at all temperatures, though its decomposition proceeds at so slow a rate below 400° C. as to be scarcely appreciable.
[15] Some clays are highly hygroscopic and absorb moisture readily from the atmosphere. According to Seger (7) this hygroscopicity distinguishes true clay from silt and dust. ”

“ The stratification of clays may be invisible throughout considerable masses, unless sandy beds are intercalated among them. Yet, when a lump of clay is dried and then placed in water, as previously described, it will often break up along parallel planes, which show that there is a regular arrangement of its particles. The fact that so many of these particles are platy becomes emphasised under the pressure of subsequent sediments, whereby the platy surfaces of the particles are brought into planes parallel with one another. ”

“ Such a clay is not a primary one as it has probably been derived from some distant source and, having been deposited along with the limestone ooze, has formed an intimate mixture from which the limestone has, at a later geological epoch, been removed in the manner indicated. Residual clays are seldom pure, being often rich in iron compounds, though the white clays of Staffordshire and Derbyshire are highly refractory. ”

“ Thus instead of stating that a certain clay when moulded into bricks, dried and burned, shrinks 18 per cent. by volume, it is customary to state that it shrinks 3/4 in. per (linear) foot. For many purposes, it is sufficient to regard the linear shrinkage as one-third the volume-shrinkage, but this is not strictly accurate.
The fusibility of clays is a characteristic which has been very imperfectly studied. Most clayworkers and investigators employ the term 'fusibility' in a special sense which is apt to be misleading. ”

“ Water, in Nature as in pottery, is the chief agent in clay working, and, besides its original action in decomposing the feldspar, it transports and grinds the original kaolin, and deposits it, in various degrees of purity or mixture, in secondary localities as a sediment. Clay material thus produced is known as sedimentary or transported clay, and, with the exception of some of the kaolins which have not been far removed from their place of origin, is more or less plastic. ”

“ Agriculturally, the Lias clays are laid down for grass, but the lighter soils are useful for arable purposes.
The 'Oolitic clays,' which are also Jurassic, usually contain limestone in the form of nodules, but are nevertheless important. They form a broad belt above the Lias from Dorset to Yorkshire, and include the blue clays of the Purbeck beds, stiff blue bituminous Kimeridge clays, the irregular, sandy Coral Rag clays, the famous Oxford clay (from which the Peterborough and Fletton bricks are made) , the Kellaways blue clay, and the Fuller's Earth deposits. ”

“ In fact, a pure clay, that is to say, a clay unmixed with sand, even though it may contain all the essential constituents of the plant, is for this reason unfertile. Practically, of course, these extreme cases rarely occur; the heaviest clay soils being mixtures of true clay with sand, and the most sandy containing their proportion of clay; but frequently the preponderance of the one over the other is so great, as to produce soils greatly inferior to those in which the mixture is more uniform. ”

“ The water may accumulate, but finally it will get through, if the clay is not too closely packed. Again it may sink rapidly through thick beds of gravel or sand. Reaching another bed of clay which is stiffer by reason of the weight of the earth above it, the water may find that it cannot soak through. The only way to pass this clay barrier is to fill the basin, and to trickle over the edge, unless a place is found in the bottom where some looser substance offers a passage. Let us suppose that a concave clay basin of considerable depth is filled with water-soaked sand. ”

“ E. H. L. Schwarz (35) has suggested that many clays are composed of small globular masses of plates so arranged as to form an open network (fig. 4) which is sufficiently strong not to be destroyed by pressure. In the presence of water and much rubbing the plates are separated and are made to lie flat on each other, thereby giving a plastic and impermeable mass. If this is really the case it would explain the porosity and large surface of some clays and might account for their adsorptive power.
Fig. 4. Illustrating the structure of a 'clay crumb.' (After Schwarz.) ”

“ In some cases after the weathering of feldspar or limestones, the clay may remain just where it was formed, as a residual deposit; but, being so fine-grained, it is usually transported by rain water or by the wind and deposited somewhere else as a sedimentary bed. The quiet waters of a lake are favorable places for such deposits, and many clay beds represent former lake bottoms. Impure clays are often laid down on the flood plains of sluggish 208 streams. In fresh water the settling of the clay is a very slow process, requiring days, or when very fine, weeks, before the water wholly clears. ”