Josiah Willard Gibbs,
Scientific Papers of Josiah Willard Gibbs
(1906)
“ We will now consider the stability of a fluid enclosed in a rigid envelop which is non-conducting to heat and impermeable to all the components of the fluid. The fluid is supposed initially homogeneous in the sense in which we have before used the word, i.e., uniform in every respect throughout its whole extent. Let be the ultimate components of the fluid; we may then consider every body which can be formed out of the fluid to be composed of , and that in only one way. Let denote the quantities of these substances in any such body, and let , denote its energy, entropy, and volume. ”
