Tear gas

“ These gases are effective in extremely low concentrations against the lungs and other air passages, or the eyes. Diphenylchloroarsine, and some other solids when divided into minute particles by high explosive or heat, irritate the nose, throat and lungs to such an extent in a concentration of one part in ten millions of air as to be unbearable in a few minutes. The tear gases are equally powerful in their effects on the eyes. The irritating gases are used to force the wearing of the mask, which in turn reduces the physical vigor and efficiency of the troops. ”

“ Yet it is one whose form can be changed, and whose hardness can be completely destroyed, by the simple process of combustion. It can be deprived of its high lustre, and of its power of breaking up by refraction the light of the sun into the various tints of the solar spectrum, simply by heating it to a red heat, and then plunging it into a jar of oxygen gas. It immediately expands, changes into a coky mass, and burns away. The product left behind is a mixture of carbon and oxygen, in the proportions in which it is met with in carbonic-anhydride, or, carbonic acid gas deprived of its water. ”

“ It may be described as a rich compact flame, burning with a white and agreeable light. It is also perfectly steady, when the flame is limited to a moderate size: in large masses, it is subject to that undulation which is common to it with all flames of certain dimensions, and is caused by the agitation of the surrounding atmosphere. The gas flame is entirely free from smell. The coal-gas itself certainly has a disagreeable foetid odour before it is burnt, so has the vapour of wax, oil, and tallow, as it comes from a lamp or candle newly blown out. ”

“ The tubes formed by the wick serve the same office as a retort placed in a heated furnace through which the inflammable liquid is transmitted. The oil is drawn up into these ignited tubes, and is decomposed into carburetted hidrogen gas, and from the combustion of this gas the illumination proceeds. See p. 15. What then does the gas-light system attempt? Nothing more than to generate, by means of sufficient furnaces and a reservoir of sufficient capacity, desired quantities of the gas, which is the same material of the flame of candles or lamps ”

“ When the fire burns bright, much radiant heat will be sent off from it; but when [150] it is smothered up, very little will be generated: most of the heat produced will then be expended in giving elasticity to a thick dense vapour, or smoke, which is seen rising from the fire; and the combustion being very incomplete, the carburetted hidrogen gas of the coal being driven up the chimney without being inflamed, the fuel is wasted to little purpose. ”

“ The same occurs when the temperature of any portion of the hydrogen is reduced below that intensity required for the combustion of the newly separated charcoal. Solid bodies, as tallow, oils, and fats, which burn with flame, are converted into the state of gas by the heat required to kindle them, and it is this gaseous matter which suffers combustion, and not the substance which produces it. ”

“ A tissue which, when red-hot, will not interrupt the flame of hydrogen, will still intercept that of olefiant gas; and a heated tissue, which would communicate explosion from a mixture of olefiant gas and air, will stop an explosion of fire-damp. Fortunately for the success of the Safety-lamp, carburetted hydrogen requires so high a temperature to carry on its combustion, that even metal, when white-hot, is far below it; and hence red-hot gauze, 147 in sufficient quantity, and of the proper degree of fineness, will abstract heat enough from the flame to extinguish it. ”

“ There is no escape of combustible matter unconsumed, which is so great a nuisance [101] in all our common lights. The products of the combustion are water and carbonic acid gas [21] . The accurate and elegant experiments of Dr. W. Henry have shewn in the most satisfactory manner, that considerably less carbonic acid is produced by the flame of coal-gas, than by that of oil, tallow, or wax [22] , which [102] sufficiently refutes the absurd notions that have been circulated respecting the pernicious effects of gas-lights. ”

“ Now if I take this test-tube of liquid derived from my treatment of the lock and then test it as you saw me do with the other, isn't that enough for you? See—it gives the same reaction."
It did, indeed, but my mind did not react with it.
"Nitrous oxide," he continued, "in contact with iron, leaves distinct traces of corrosion, discernible by chemical and microscopic tests quite as well as the marks it leaves in the human blood. Manifestly, if no one could have come in by the windows or doors, the gas must have been administered in some way without any one coming into the room. ”

“ It appears from these experiments that silica, charcoal, lampblack, and oxide of bismuth all increase the heat insulations to four, five and six times that of the empty vacuum space. As the chief communication of heat through an exhausted space is by molecular bombardment, the fine powders must shorten the free path of the gaseous molecules, and the slow conduction of heat through the porous mass must make the conveyance of heat-energy more difficult than when the gas molecules can impinge upon the relatively hot outer glass surface, and then directly on the cold one without interruption. ”

“ Each addition of animal matter causes a somewhat violent frothing and escape of combustible [55] gases, along with water and carbonic acid, and the whole becomes thick—not so much owing to the introduction of solid substances as by the fall of temperature, resulting from the production of such large quantities of gas. In order to hasten the decomposition, vigorous stirring must be applied. When the reaction is at an end, the semi-fluid mass is transferred to cast-iron dishes, and the furnace is again filled with carbonate of potash and heated. ”

“ It would certainly be esteemed one of the greatest discoveries of the age if any one could succeed in condensing coal gas into a white, dry, solid, odourless substance, portable, and capable of being placed upon a candlestick, or burned in a lamp. Wax, tallow, and oil, are combustible gases in a solid or fluid form, which offer many advantages for lighting, not possessed by gas: they furnish, in well-constructed lamps, as much light, without requiring the expensive apparatus necessary for the combustion of gas, and they are generally more economical. ”

“ The flame produced from coal, wood, turf, oil, wax, tallow, or other bodies, which are composed of carbon, hydrogen and oxigen, proceeds from the production of carburetted hydrogen gas, evolved from the combustible body when in an ignited state.
It must have been noticed at the same time, that in the common mode of burning coal in a fire-place, or stove, nearly the whole of this inflammable gaseous matter is lost. We often see a flame suddenly burst from the densest smoke, and as suddenly disappear ”

“ The quantities of heat and light produced by the combustion of inflammable gases are by no means in the same constant relation to each other; one frequently increases, whilst the other diminishes; and this is eminently the case when coal gas and oil gas are burned against each other. The quantity of heat liberated is, speaking generally, as the quantity of gas consumed, and this is greatest with the coal gas; but the quantity of light is nearly as the quantity of carbon that is well burnt in the flame, and this is greatest in the oil gas. ”

“ When the carbonic acid is absorbed by lime-water, if the gasses have been properly proportioned, no gazeous residue is left, except accidental impurities. Though carburetted hydrogen gas, is sometimes naturally produced in coal-mines, and occasionally mixes with common air, producing dreadful explosions, yet when coal-gas is mixed with common air, it does not explode unless the gas be to the air as 1 to 10 nearly. Such are the leading chemical habitudes of this gazeous product. The varieties of carburetted hydrogen gas all agree in being inflammable ”

“ The metallic gauze so rapidly conducts away the heat, that the temperature of the gas beneath the gauze is unable to arrive at the point of ignition. In the safety-lamp the little oil-lamp is placed in a circular funnel of fine gauze, which prevents the flame from passing through it to any explosive gas that may be floating about outside, but at the same time allows the rays of light to pass through readily. ”

“ Now, when I take a piece of fine gauze, the flame does not pass through at all until the gauze is nearly red-hot. There is plenty of gas passing all the time. If I take a still finer gauze, I shall find that the flame won't pass even when it is almost red-hot (Fig. 32 B) . Plenty of gas is passing through, remember, all the time, but the flame does not pass through. Now why is it that the flame is unable to pass? The reason is this—because the metal gauze has so cooled the flame that the heat on one side is not sufficient to set fire to the gas on the other side. ”

“ Some mines are cursed with firedamp, that light thin gas which, floating on the heavier air, steals along the splintered roof of coal seams and gradually displaces the pure fresh current from the surface fans. But the bane of Neddrie No. 2 was carbonic acid gas, which, heavier than air, crawled along its floors and slowly rose, ankle-high, knee-high, breast-high, face-high, till it choked the life out of those who might be caught in its deadly embrace. ”

“ But it is true with respect to lead, and some other noxious metals, because, unless care be taken, the particles of the oxyd which are volatilised by the heat are inhaled in with the breath, and may produce dangerous effects.
I must show you some instances of the combustion of metals; it would require the heat of a furnace to make them burn in the common air, but if we supply them with a stream of oxygen gas, we may easily accomplish it. ”

“ But let us go a step further: why must the solid sulphur be converted into a gas? We want a flame, and whenever we have flame it is absolutely necessary that we should have a gas to burn. You cannot have flame without you have gas. Let me endeavour to illustrate what I mean. I pour into this flask a small quantity of ether, a liquid easily converted into a gas. If I apply a lighted taper to the mouth of the flask, no gas, or practically none, being evolved at the moment, nothing happens. But I will heat the ether so as to convert it into a gas. ”

“ If coal be distilled with a very low red heat scarcely observable by daylight, the gas produced gives a feeble light—if the temperature be increased so that the distillatory vessel is of a dull redness, the light is more brilliant and of a better colour—if a bright or cherry-red heat be employed the gas produced, burns with a brilliant white flame, and if the heat be increased so far that the retort is almost white hot, and consequently in danger of melting, the gas given out, has little illuminating power, and burns with a clear blueish flame ”

“ This may be effected by causing a current of air to rise up perpendicular from the bottom of the chimney glass, and to pass out again through the contracted part, or upper extremity of the chimney; but no other current of air should ever be permitted to come near the gas-flame, or enter the glass chimney which covers or defends the light; for if more air be permitted to mix with the flame than is sufficient for the compleat combustion of the coal-gas, it necessarily diminishes the heat, and consequently reduces the quantity of light. ”

“ As the proportion of light given out by the flame of a gaseous compound of carbon and hydrogen, is in common circumstances in proportion to the quantity of carbon present; it is evident that the gas which contains a greater proportion of olifiant gas, or supercarburetted hydrogen than coal gas, will yield a better and brighter light on combustion. ”

“ The chief danger with an apparatus of this sort is its liability to accident by the careless use of the gas, and, as a mixture of hydrogen and air is very explosive, great care must be taken to exhaust all the air in the generator and tubes before attempting to light the gas at the blow pipe. The only way to make sure that the air is exhausted is to test the gas, as described under the head of “The Flame and Its Management.” ”

“ He had observed that, when the coal gas burnt in the iron cage, its colour was pale, and its light feeble; whereas the fact is rendered familiar to us all by the flame of the gas lights, that in the open air carburetted hydrogen burns with great brilliancy. Upon reflecting on the circumstances of the two species of combustion, he was led to believe that the cause of the superiority of the light in the latter case might be owing to a decomposition of a part of the gas towards the interior of the flame, where the air was in the smallest quantity ”

“ They are consequently as far as possible removed as impurities in the process of gas-making. These are nitrogen, carbonic acid gas, and the destructive sulphur compounds, sulphuretted hydrogen and carbon bisulphide vapour. It is to the last two to which are to be attributed the injurious effects which the burning of gas has upon pictures, books, and also the tarnishing which metal fittings suffer where gas is burnt, since they give rise to the formation of oil of vitriol (sulphuric acid) , which is being incessantly poured into the air. ”

“ When coals are heated in a cast-iron retort to ignition, the progress of decomposition is as follows. First, and before the retort becomes red hot, steam issues along with the atmospheric air. When the retort begins to redden, tar distils in considerable quantity with some combustible gas, of which hydrogen mixed with ammoniacal gas forms a part. The evolution of gas increases as the retort becomes hotter, with a continual production of tar and ammoniacal liquor as well as sulphurous acid from the pyrites of the coal, which unites with the ammonia. ”