S. D. Humphrey

“ When an impression is dark, the gilding process may be longer continued; but when light, it should be gilded quickly, as lengthening the time tends to bleach the impression and make it too white. The cause of this appears to be, that with a moderate heat the chlorine is merely set free from the gold, and remaining in the solution, instead of being driven off, with its powerful bleaching, properties, it immediately acts upon the shades of the picture. A dark impression can thus, by a low heat, long-continued, be made quite light. ”

“ It is necessary, first of all, to know that you have a chemical which is capable of producing good results when in skillful hands. For this reason it is best to prepare your own quick, after some formula which is known to be good. Those quick-stuffs which contain chloride of iodine are noted for their depth of tone while they probably operate with less uniformity than those which are destitute of it. For operating under ordinary circumstances, especially with an inferior light, probably no accelerator is more quick and sure than Wolcott’s. ”

“ The great object, therefore, is to maintain, as nearly as possible, a perfect balance between the two elements entering into union to form the sensitive coating of the plate, in order that the lights and shades be truly and faithfully represented, and that all objects, whether light or dark, be made to appear so far conformable to nature, as is consistent with the difference in the photogenic energy of the different colored rays of light. ”

“ Make a saturated solution of salt in water. First wash the plate with clear water; then immerse it in the saline solution, when it should be agitated, and the coating will soon disappear. Another process with a salt solution of half the strength of the above is very interesting and effectual. The plate having been dipped into cold water, is placed in a solution of common salt, of moderate strength; it lies without being acted upon at all; but if it be now touched on one corner with a piece of zinc, which has been scraped bright, the yellow coat of iodine moves off like a wave and disappears. ”

“ Light is white and colorless, as long as it does not come in contact with matter. When in apposition with any body, it suffers variable degrees of decomposition, resulting in color, as by reflection, dispersion, refraction, and unequal absorption.
To Sir I. Newton the world is indebted for proving the compound nature of a ray of white light emitted from the sun. The object of this work is not to engage in an extended theory upon the subject of light, but to recur only to some points of more particular interest to the photographic operator. ”

“ It is a fact not generally known, that a plate coated in a light chemical room is more sensitive than when coated in darkness. By admitting a free, uniform light, and exposing the plate to it a few seconds after coating, then timing short in the camera, a very light, clear impression is obtained. The time in the camera is reduced in proportion to the previous action of light. The shades, of course, are destroyed, and the tone injured; still, for taking children, we have succeeded better by this method than by the use of “sensitives.” ”

“ Experience proves that the common impressions, iodized to a rather light yellow gold tint, and brought by the bromine to a very light, rose color, have their whites very intense, and their deep shades very black. It is also known that if you employ a thicker coating of iodine and apply upon it a proportionate tint of bromine, so as to obtain a deep rose tint, delineations will be less marked, and the image have a softer tone. This effect has been obvious to everyone who has practised the art. ”

“ The principal difficulty in coating the plate, is that of preserving the exact proportion between the quantity of iodine and bromine, or quick. It is here necessary to say, that hardly any two persons see alike the same degree of color, so as to be enabled to judge correctly the exact tint, i. e. what one might describe as light rose red, might appear to another as bright or cherry red; consequently, the only rule for the student in Daguerreotype, is to study what appears to him to be the particular tint or shade required to aid him to produce the desired result. ”

“ While it is true that a little color may relieve the dark metallic look of some Daguerreotypes, it must not be concealed that the covering of the fine delicate outline and exquisite gradations of tone of a good picture with such a coating, is barbarous and unartistic. ”

“ At the suggestion of Professor Mapes (who is ever ready to assist those in perplexity) , a trough of plate glass s, about twenty-eight inches square in the clear, and from three to four inches thick, was filled with a solution of ammonia sulphate of copper, and mounted on the frame as in the sketch, which, for a time, answered extremely well; soon, however, decomposition of this solution became apparent from the increased length of time required for a sitting, although to the eye of an observer, no visible cause for such long sittings could be pointed out. ”

“ Every experienced operator has in a degree become familiar with the mechanical uses of all the agents employed, while I fear but few understand the properties, and laws governing those properties, which are so indispensable to produce an image impressed upon the silver surface.
There are three substances which form the bases for producing a Daguerreotype; silver, iodine and bromine. Each forms a separate body which is indispensable to the operators success as the art is now practiced in America. ”

“ This is at best a disagreeable process to conduct, for the hydrocyanic acid formed adheres so strongly to the glass, that, instead of being freely given off, bubbles are evolved suddenly with such explosive violence as occasionally to crack the vessel. This may be remedied as far as possible by the insertion of plenty of waste pieces of platinum—if platinized, so much the better, as that facilitates the escape of the gas. The heat should be applied to every part of the vessel, and the flame should not be allowed to play upon one single part alone. ”

“ Reflectors for Taking Views.—There have been excellent cameras introduced for taking views, but the time of exposure, which is increased in proportion to the focal length, is considered an objection; consequently many adhere to the old plan of using the speculum, or rather, substitute a mirror. I now have one which I have used for several years and find it equal to any article of the kind have ever tried. One is easily made by a tin man, at a trifling expense. Procure a piece of best plate looking-glass, two and a half by five inches for a quarter, or four by eight for a half-sized camera ”

“ By adding iodide of potassium to a solution of nitrate of silver, a yellowish-white precipitate of iodide of silver is obtained, which is insoluble in water, slightly soluble in nitric acid, and soluble in a small degree in ammonia, which properties seem easily to distinguish it from the chloride and bromide of silver. Chlorine decomposes it and sets the iodine free, and chlorohydric acid converts it into a chloride. It fuses below a red heat. ”

“ Artificial lights differ in their color; the white light of burning charcoal, which is the principal light from candles, oil and gas, contains three rays—red, yellow, and blue. The dazzling light emitted from lime intensely heated, known as the Drummond light, gives the colors of the prism almost as bright as the solar spectrum.
If we expose a prepared Daguerreotype plate or sensitive paper to the solar spectrum, it will be observed that the luminous power (the yellow) occupies but a small space compared with the influence of heat and chemical power. ”

“ Then, if we examine, with respect to strength, or depth of tone, and sharpness of impression, we see that the light coating, produces a very sharp but shallow impression; while the other extreme gives a deep but very dull one. Here, then, are still better reasons for avoiding either extreme. The changes through which the plate passes in coating may be considered a yellow straw color or dark orange yellow, a rose color more or less dark in tint, or red violet, steel blue or indigo, and lastly green. ”

“ From my own experiments, I have found that a plate, by being galvanized, can be rendered more sensitive to the operation of the light in proportion of one to five, viz.: if a plate as furnished by the market, be cleaned, polished, coated and exposed in the camera, if the required time to freely develop an impression be ten seconds, a similar plate prepared in like manner and galvanized, will produce an equally well-defined image in eight seconds. ”

“ The carbonate of the metal rapidly changes to an oxide by contact with the air, and it will generally be found, when it is sufficiently washed, that it is at least half oxide. On adding hydrochloric acid cautiously to the mixture, a chloric of the metal will be formed, and carbonic acid will be evolved from the remaining carbonate. The chloride formed is soluble; but as there are two chlorides of these metals, and we wish to produce the one which contains the most chlorine, it is best to add the acid cautiously until the solution is decidedly acid. ”

“ The mixture should be stirred often with a glass rod; care should be observed not to apply too much heat, for at a temperature of about 300 deg. the chlorine would be expelled and leave a metallic precipitate, which would require re-dissolving. Acid may at any time be added if necessary to dissolve the gold, but it is advisable to add as little excess as possible, as it would require more time to evaporate. After all the gold has dissolved, and the liquid assumes a deep red color, the solution should be allowed to cool, being stirred nearly all the time. This salt is of a reddish-brown color. ”

“ Water recently boiled will absorb, if cold, about twice its bulk of chlorine gas, acquiring its color and characteristic properties. The moist gas, exposed to a cold of 32 deg., yields beautiful yellow crystals, which are a definite compound of one equivalent of chlorine and ten of water. If these crystals are hermetically sealed up in a glass tube, they will, on melting, exert such a pressure as to liquefy a portion of the gas, which is distinctly seen as a yellow fluid, not miscible with the water which is present. ”

“ Agent for Neutralizing Bromine, Chlorine, and Iodine Vapors.—Aqua ammonia, sprinkled about the chemical or coating room, will soon neutralize all the vapor in the atmosphere of either chlorine, bromine, or iodine. No operator should be without, at least, a six-ounce bottle filled with ammonia. A little of its vapor about the camera-box has a decided and happy effect. Burnt coffee, pulverized, has also the property of destroying the vapors of the above chemicals, as also almost any other agent employed about the Daguerreotype room. ”

“ For various reasons I prefer a high temperature and short exposure. It accelerates the process. It renders the lights of the picture more strong and clear, while the deep shades are more intense. It gives a finer lustre to the drapery. The solarized portions also are very seldom blue, especially after gilding. If heated too high, however, the light parts become of a dead, chalky white, and the shadows are injured by numerous little globules of mercury deposited over them. ”

“ Solarization, and general blueness of all the light parts of the picture, were formerly great obstacles to success, though now scarcely thought of by first-class artists. Beginners in the art, however, are still apt to meet with this difficulty. It is occasioned by dampness in the iodine box, which causes the plate to become coated with a hydro-iodide of silver, instead of the iodide. ”

“ It is well known to the experienced Daguerreotypist, that different atmospheres have a decided effect upon the mercury in developing the Daguerreotype. It will require a greater degree of heat for one atmosphere than for another. Experience alone determines this little difference.
In summer, on cloudy and stormy days, mercurial vapors rise more readily and quickly than in the temperature of autumn or winter. From 60 degrees upwards towards the boiling point (660 deg.) , the vapors of mercury rise in greater abundance and collect in larger globules on cold surfaces. ”

“ Take pure rain or distilled water, one quart, filter through paper into a ground stopper bottle, and add, for warm weather, one and a half ounce chloride of iodine; or for cold, one ounce; then add one ounce bromine, and shake well. Now with care not to allow the vapor to escape, add drop by drop, thirty drops of aqua ammonia, shaking well at each drop. Care must be taken not to add more at a time, as it evokes too much heat. This mixed, in equal proportions with John Roach’s quick, forms an excellent chemical combination. ”

“ It should be observed that at the surface of bodies the refractive power is exerted, and that the light proceeds in a straight line until leaving the body. The refraction is more or less, and in all cases in proportion as the rays fall more or less obliquely on the refracting surface. It is this law of optics which has given rise to the lenses in our camera tubes, by which means we are enabled to secure a well-delineated representation of any object we choose to picture. ”