Inorganic matter

“ But that is a matter of inorganic chemistry, you say. Very true. But I dare to assert, standing here on my two feet, that in the organic I can duplicate whatever occurs in the inorganic.
“Here!” He held a test-tube between me and the light, and I noted the cloudy or muddy liquid it contained. He emptied the contents of another test-tube into it, and almost instantly it became clear and sparkling.
“Or here!” With quick, nervous movements among his array of test-tubes, he turned a white solution to a wine color, and a light yellow solution to a dark brown. ”

“ It must not be understood that this force, which I finally came to control, annihilated matter; it merely annihilated form. Nor, as I soon discovered, had it any effect on inorganic structure; but to all organic form it was absolutely fatal. This partiality puzzled me at first, though had I stopped to think deeper I would have seen through it. Since the number of atoms in organic molecules is far greater than in the most complex mineral molecules, organic compounds are characterized by their instability and the ease with which they are split up by physical forces and chemical reagents. ”

“ All inorganic masses increase in size only by the accretion of particles—layer upon layer, without any chemical change taking place as an essentiality. The sun may shine for ages upon a stone without quickening it into life, changing its constitution, or adding to its mass. Organic matter consists of arrangements of cells or sacs, and the increase in size is due to the absorption of gaseous matter, through the fine tissue of which they are composed. The gas—a compound of carbon and oxygen—is decomposed by the excitement induced by light ”

“ The properties of matter are so distributed among the elements that three of them—Oxygen, Hydrogen, and Carbon—possess an ensemble of unique characteristics. The number of reactions in inorganic chemistry are relatively few, but in organic chemistry—in the chemistry of these three elements the number of different compounds is practically unlimited. ”

“ "In the pursuit of my investigations I was unconsciously led into the border region of physics and physiology. To my amazement, I found boundary lines vanishing, and points of contact emerging, between the realms of the living and the non-living. Inorganic matter was perceived as anything but inert; it was athrill under the action of multitudinous forces.
"A universal reaction seemed to bring metal, plant and animal under a common law. ”

“ The higher the molecular tower, or the more atoms it contains, the greater its liability to fall. Some organic compounds contain hundreds of atoms, and hence are easily broken down, or, as we say, are unstable. Inorganic compounds are, as a rule, much more stable than organic ones. It is not always true, however, that the compound with the least number of atoms is the most stable. SO2 is more stable than SO3, but H2SO3 is less so than H2SO4. Chapter XXXIV.
VAPOR DENSITY AND MOLECULAR WEIGHT. Examine a liter measure, in the form of a cube,—cubic decimeter, —and a cubic centimeter. ”

“ The great majority of the compounds found in living organisms contain carbon, and the term "organic chemistry," as used at present, includes not only these compounds but all compounds of carbon. Organic chemistry has become, therefore, the chemistry of the compounds of carbon, all other substances being treated under the head of inorganic chemistry. This separation of the compounds of carbon into a group by themselves is made almost necessary by their great number, over one hundred thousand having been recorded. ”

“ The view long maintained—until late in the nineteenth century, in fact—that organic and inorganic chemistry are separated from each other by a wide gap, is no longer held. Hundreds of organic substances, some of them of great complexity, have been made in the chemist’s laboratory, and can now be classed as properly with inorganic as with organic substances. The gap has been closed, and there is now but one chemistry. Only the most intricate chemical compounds still lie beyond the chemist’s grasp, and the isolation of these may be at any time overthrown. ”

“ On the contrary, we live in the hope and in the faith that, by the advance of molecular physics, we shall by-and-by be able to see our way as clearly from the constituents of water to the properties of water, as we are now able to deduce the operations of a watch from the form of its parts and the manner in which they are put together. Is the case in any way changed when carbonic acid, water and ammonia disappear, and in their place, under the influence of preëxisting living protoplasm, an equivalent weight of the matter of life makes its appearance? ”

“ The new branch of inorganic chemistry called physical chemistry has given us entirely new ideas of the nature of solutions, and the fact that electrolytes in solution are broken up into their constituent ions is one of fundamental importance. ”

“ The chemical elements include oxygen, silicon, calcium, sulfur, carbon, gold, silver, and many others. There are 90 naturally occurring elements. Each is made up of molecules that consist of only one kind of atom. Chemical elements may either be combined with each other or occur alone. They are the building blocks of our world for they make up all the gases, all the liquids, all the minerals, all the plant and animal life, and all the other physical matter. Some of the chemical elements that occur in the rocks and minerals mentioned in this book are listed below. ”

“ Chemical analysis associated with physical analysis by means of the polariscope, spectroscope, x-rays, ultramicroscope, etc. is extremely useful in determining the structure of inorganic units like the atom and the molecule. Both, too, throw valuable light on the problem of the structure of non-living multimolecules such as the crystal units of crystalloids and the ultramicrons of colloids, but they furnish no clue to the submicroscopical morphology of the living cell. ”

“ An inorganic substance, on the contrary, however complex its formula may appear, is actually built up of binary compounds, the simplest that can be formed. But in the organic substance the carbon and hydrogen have a strong tendency to form carbonic acid; the hydrogen and oxygen to form water; the hydrogen and nitrogen to form ammonia; or, the hydrogen and the sulphur to form sulphuretted hydrogen, &c. In popular language, these changes are expressed by such terms as decay and putrefaction. ”

“ The fundamental task of inorganic chemistry is still connected with the classification of elements and compounds. The investigation of the classification of carbon compounds forms the field of organic chemistry; while general or physical chemistry deals with the laws of reaction, and the influence of various forms of energy in furthering or hindering chemical change. ”

“ In the fact that living creatures always consist of the four elements, oxygen, hydrogen, nitrogen and carbon, we have a fundamental character whereby the organic and inorganic (or non-living) worlds are to be [pg 360] distinguished, for as we have seen, inorganic bodies, instead of being thus uniformly constituted, may consist of the most diverse elements and sometimes of but two or even of only one. ”

“ If we take a piece of iron or gold there is no process known by which we can resolve it into simpler form, and these are therefore elements. There are over sixty elements and many of them are found in the human body. All these elements are derived from unorganized matter, and the special conditions under which they are formed in organisms is due to the principle of life. The predominant elements that make up the human body are carbon, hydrogen, oxygen, and nitrogen, while iron, potassium, sodium, phosphorous, calcium, exist in smaller quantity. ”

“ As an element, oxygen possesses a known chemical individuality, and an influence on the properties of those combinations into which it enters. Hydrogen gas is a substance which reacts with difficulty, but the element hydrogen represents in its combinations an easily displaceable component part. Carbon may be considered as an atom of carbon matter, and charcoal as a collection of such atoms forming a whole substance, or mass of molecules of the substance. ”

“ For a similar reason the study of inorganic chemistry naturally precedes the study of organic chemistry, because inorganic compounds are much simpler and therefore more easily analysed and investigated than organic compounds. ”

“ In the inorganic section we shall become acquainted with the elements and their combinations so often seen as minerals in nature. Chemical preparations are artificially prepared. To consider these elements we must have certain appliances, and indeed a laboratory is needed. Heat, as we have already seen, plays a great part in developing substances, and by means of heat we can do a great deal in the way of chemical decomposition. It expands, and thus diminishes cohesion; it counteracts the chemical attraction. Light and electricity also decompose chemical combinations. ”

“ This kind of truth can never be revealed to us by the study of inorganic aggregations of the universe. The molar, molecular, and polar forces, by which they are formed, may be expressed, so far as science has reduced them to order, by a small number of simply formulated laws, indicative neither of purpose nor intelligence, when confined within inorganic limits. In fact, taking also the organic world into consideration, we as yet see no reason why the number of chemical elements known to us should be as large as it is, and go on increasing almost yearly with more minute investigations. ”

“ By means of the electric furnace, Moissan, in France, has succeeded in uniting carbon with many of the metallic elements, and thus opened the path for new achievements in passing directly from inorganic to organic compounds.
202 The progress of chemical synthesis has already blotted out the old distinction between inorganic and organic chemistry, and we can no longer say of organic bodies that they are the products of living cells. Organic bodies are those which contain a carbon or other elementary skeleton, to which are attached the elements or groups of elements forming the complete body. ”

“ We are therefore entitled to declare that this substance consists of ultimate particles, which can not be divided without changing them into other kinds of matter. These are its molecules. Next, in the light of chemical synthesis, also, we may see the existence of these ultimate particles.
Hydrogen and oxygen are the inevitable constituents of water, and two volumes of hydrogen to one volume of oxygen are the invariable proportions. No human agency can obtain water by combining any other elements, nor by combining these in any other proportions. ”

“ The atoms of the ultimate molecules of both organic and inorganic bodies are identically the same. It depends entirely upon what particular combination of atoms takes place whether an organic or inorganic form is developed. ”

“ The inorganic chemical compounds contain oxygen as the most general constituent, while the organic compounds contain as generally carbon. Hence, if we were to mystify some of our chemical colleagues, not very sound in elementary mathematics, we would calculate the densities of all compounds by assuming almost any fixed atomic volume for these two elements, and assigning the residual volume to the other constituents. ”

“ The reason is that the capacity of ordinary matter for stopping the rays varies approximately as the fourth power of the atomic number of the elements concerned. Thus carbon, whose atomic number is 6, is 1296 times as effective as hydrogen in stopping X-rays; oxygen, whose atomic number is 8, is 4096 times as effective as hydrogen; nitrogen, whose atomic number is 7, is 2401 times as effective as hydrogen; calcium, whose atomic number is 20, is 160,000 as effective as hydrogen. The human body consists mainly of carbon, oxygen, nitrogen and hydrogen, but the bones consist mainly of calcium. ”

“ Besides the characteristic substances of these three classes, protoplasm contains certain other chemical compounds, like the various salts of sodium, chlorine, magnesium and potassium, and a few others, which bring the list of chemical elements to the number twelve. We have already noted how strikingly small and restricted is the list of elements composing living matter as compared with the long array of eighty-odd different kinds of chemical atoms existing in the world as a whole. ”

“ Carbon, hydrogen, and oxygen, plus varying proportions of phosphorus, potassium, iodine, nitrogen, sulfur, calcium, iron, magnesium, manganese, and strontium, plus a smattering of trace elements, seem to be able to cook up all kinds of life under the strangest imaginable conditions. ”

“ Whether hydrogen, carbon, nitrogen, oxygen, or any of the other abundant elements having small molecules have entered into the composition of these heavy substances, is a legitimate question. The fact that these molecules are stable, whether combined or uncombined, is favorable to this view, although there may exist, as component units of the molecules of the metals, many equally stable aggregates which no human power can dissociate from their present combinations. ”

“ These compounds, resolved into their elements by the processes of chemistry, yield a certain number (fifty-five) of substances which, under the conditions yet applied to them, are found to be incapable of further analysis, and are therefore called simple or elementary substances. They are singularly diversified in weight, mode of existence when separate, and relation to temperature and electricity.
In a free state under ordinary pressure and temperature, some (five) exist as gas; viz., hydrogen, oxygen, chlorine, fluorine, azote. Seven are non-metallic solids and liquids ”

“ Take a piece of red-hot matter, and however evenly heated it may at first be, it will quickly cease to be so: the exterior, cooling faster than the interior, will become different in temperature from it. And the lapse into heterogeneity of temperature, so obvious in this extreme case, is ever taking place more or less in all cases. The actions of chemical forces supply other illus [83] trations. Expose a fragment of metal to air or water, and in course of time it will be coated with a film of oxide, carbonate, or other compound: its outer parts will become unlike its inner parts. ”