Iron (metal)

“ That iron should have been one of the last of the metals to come into general use, is partly accounted for by the circumstance that iron, though one of the most generally diffused of minerals, never presents itself in a natural state, except in meteorites; and that to recognise its ores, and then to separate the metal from its matrix, demands the exercise of no small amount of observation and invention. ”

“ Pure iron is never obtained commercially, the metal always being mixed with various proportions of carbon, silicon, sulphur, phosphorus, and other elements, making it more or less suitable for different purposes. Iron is magnetic to the extent that it is attracted by magnets, but it does not retain magnetism itself, as does steel. Iron forms, with other elements, many important combinations, such as its alloys, oxides, and sulphates. ”

“ The principal iron ores are the oxides and carbonates, and these readily yield the metal by smelting with carbon. The metal so obtained invariably contains a certain amount of carbon, free or combined, and the proportion and condition regulate the properties of the metal, giving origin to the three important varieties: cast iron, steel, wrought iron. The perfectly pure metal may be prepared by heating the oxide or oxalate in a current of hydrogen; when obtained at a low temperature it is a black powder which oxidizes in air with incandescence ”

“ The strength of iron is at its maximum in the smallest mechanical structures.
2. The quality of the metal is improved as it is subjected to greater pressure and condensation.
The extent to which this improvement may be carried has never yet been ascertained; every fresh manipulation improves its quality. The tenacity of wrought iron is best displayed in a wire, drawn out until it is not thicker than a human hair. Large masses of wrought iron are weak and spongy in geometrical progression with the mass, and the crystalline or molecular form increases with the mass. ”

“ Again, iron which has been excited by a loadstone, * if that iron on account of obstacles should not be able to turn round immediately in accordance with its nature, as happens with a versorium, is laid hold of, when a loadstone approaches, on either side or at either end. Because, just as it can implant, so it can suddenly change the polarity and turn about the formal energies to any part whatever. So variously can iron be transformed when its form is adventitious and has not yet been long resident in the metal. ”

“ IRON MINES. The metal which is called iron, is familiar to all, both for its value and its various uses. It is capable of being cast in molds of any form; of being drawn in wires, extended in plates or sheets, of being bent in every direction, and of being sharpened, hardened, or softened at pleasure. It accommodates itself to all our wants, desires, and even caprices; it is equally serviceable to the arts, the sciences, to agriculture, and to war ”

“ Iron ores are to be found almost everywhere. But of all the different kinds the palm of excellence is awarded to that which is made by the Seres, who send it to us with their tissues and skins; next to which, in quality, is the Parthian iron. None of the other kinds of iron are made of the pure hard metal, a softer alloy being welded with them all. In our part of the world, a vein of ore is occasionally found to yield a metal of this high quality, as in Noricum, but in other cases, it derives its value from the mode of working it. ”

“ Shalyam specifically denotes an article of iron, inasmuch as it pre-eminently serves the purpose of killing and is the most irresistible of all metals. Since any amount of sharpness can be imparted to the point of an article made of iron and since it can be easily discharged from a distance, iron is the metal exclusively chosen in the construction of darts or arrows. ”

“ Iron is a metal of a bluish gray colour; but in its pure state it looks almost white when polished, and has a brilliant lustre, while when it is broken the broken portion looks dull and fibrous. It is the hardest of all the malleable and ductile metals, and the most tenacious of all metals, an iron wire of 1⁄36th of an inch in diameter bearing a weight of 60 pounds. ”

“ Certainly not as the metal iron, for every property of the metal will have disappeared. The crystals are brittle, can be crushed in a mortar—they are translucent—they show no metallic lustre, but only glassy surfaces—they are readily dissolved by water—they are not attracted by a magnet. The most powerful lens will fail to show the least particle of iron in them; they have in their properties no assignable relation to the metal of the nails, but are matter of quite another sort; and be it noted that this entire otherness is the special and characteristic sign of chemical change. ”

“ Though many trials have been made in working extra-terrestrial metal, all have hitherto failed; the phosphorus, nickel and its alter ego, cobalt, render the forgings, in our present state of technology, too brittle for use. Terrestrial or telluric iron is again divided into two classes—the nearly pure ore and the native steel. According to the schedule of Rosset:
100
Iron is a metal not cast and malleable. ”

“ Iron is the commonest of all metals: nay, it is so universally diffused through the earth, that it is difficult to find any stone, earth, or sand, that does not contain some of it; and therefore none of these are usually considered and treated as iron ores, except such as contain a great deal of that metal, and melt easily. The hematites, emery, yellow pyrites, calamine, all contain a pretty considerable quantity of iron ”

“ Primitive furnace for smelting iron ore.
Not many of us have ever seen iron, the pure metal, soft, ductile and white like silver. As soon as it is exposed to the air it veils itself with a thin film of rust and becomes black and then red. For that reason there is practically no iron in the world except what man has made. It is rarer than gold, than diamonds; we find in the earth no nuggets or crystals of it the size of the fist as we find of these. But occasionally there fall down upon us out of the clear sky great chunks of it weighing tons. These meteorites are the mavericks of the universe. ”

“ It is so highly 75refined that it can hardly be called steel at all but is often called “open-hearth iron” or “ingot iron.” It is probably the purest iron on the market in commercial quantities to-day. While in the chemical laboratory iron of considerably greater purity can be made, for a commercial product this is remarkably pure, seldom containing more than 1⁄4 per cent of elements other than the metal, iron. ”

“ Their antipathy to the metal furnishes men with a weapon which may be turned against the spirits when occasion serves. As their dislike of iron is supposed to be so great that they will not approach persons and things protected by the obnoxious metal, iron may obviously be employed as a charm for banning ghosts and other dangerous spirits. And often it is so used. Thus in the Highlands of Scotland the great safeguard against the elfin race is iron, or, better yet, steel. The metal in any form, whether as a sword, a knife, a gun-barrel, or what not, is all-powerful for this purpose. ”

“ One has no difficulty in realizing that these flakes, which cut in every direction through the metal, make it structurally weak, especially toward a sudden blow.
No. 1d shows a typical section of wrought iron cut lengthwise of the rolled bar. It will be noted that, as in photomicrograph No. 99b, there are no graphite flakes.
In the process of wrought iron manufacture practically all of the carbon of the original pig iron is burned out, leaving little besides the iron itself and some viscous cinder or slag. ”

“ It usually contains from 60 to 70 of metallic iron in 100 parts; the equivalent proportion of oxygen in the pure red oxide of iron being 30 parts combined with 70 of metal. It is a mistake to suppose any specular iron ore capable of yielding 85 per cent. of iron, for 100 parts of even protoxide of iron contain only 77·77 parts of metal.
The compact variety comprises the crystals of the island of Elba, and of Framont in the Vosges, which have a rough-grained fracture. It exists in very great masses, constituting even entire mountains ”

“ This is the most useful metal we have. When it is pure it has a silvery color, is very tenacious, which means that it is tough; it is malleable, that is it can be hammered without cracking, and it is ductile in that it can be drawn out into wire without breaking.
It is hard to get pure iron for nearly all of it contains a small percent of carbon, silica, phosphorus, sulphur or other elements. These substances in iron give it different properties. For instance cast-iron has a large amount of carbon in it ”

“ It has been repeatedly shown above that iron not excited by a stone turns north and south; further that it has verticity, that is, special and peculiar polar distinctions, just as a loadstone, or iron which has been rubbed upon a loadstone. This indeed seemed to us at first wonderful and incredible; the metal of iron from the mine is smelted in the furnace; it runs out of the furnace, and hardens into a great mass; this mass is divided in great worksteads, and is drawn into iron bars, from which smiths again construct many instruments and necessary pieces of iron-work. ”

“ B. The native nickeliferous or meteoric iron is very malleable, often cellular, but sometimes compact, and in parallel plates, which pass into rhomboids or octahedrons. It is naturally magnetic, and by its nickel is distinguishable from terrestrial native iron. Macquart, in describing the famous mass found at mount Kemir in Siberia, says that the iron is perfectly flexible, and fit for making small instruments at a moderate heat; but in too strong a fire, the metal becomes short, brittle, and falls into grains under the hammer. ”

“ We say that the iron made by the ancients was in reality a variety of what we now term wrought iron, for it fulfilled three of the principal requirements for wrought iron, viz., it was not necessarily melted during production, it was a malleable metal, and it contained cinder or slag, but practically no carbon. ”

“ Iron is by all reckoned in the class of metals, and is a metal livid in colour, very hard, glows red-hot before it melts, being most difficult of fusion, is beaten out under the hammer, and is very resonant. ”

“ On the application of heat in furnaces, constructed for the purpose, the charcoal unites with the oxygen of the oxide, reducing it to the metallic state, and escapes in the form of carbonic acid; and the lime, if the ore be argillaceous, unites with the clay, forming a kind of glass, which floats on the melted metal. When the iron is suffered to run into moulds, prepared for its reception, it usually takes the name of pig iron.
Manufacturers distinguish cast iron by its colour and other qualities. The white cast iron is hard and brittle, and can neither be filed, bored, nor bent. ”

“ But since modern methods of manufacturing have been adopted, tons of metal, which would have been classed as iron if judged by the cooling test, are at present known as mild or soft steel.
Steel may properly be defined as an alloy of iron with carbon, the latter not exceeding 1.8 per cent; the materials are completely fused and poured into molds, allowed to cool, and then rolled into shape. In the processes of making wrought iron the materials are only partly fused and are not cast into molds, but are taken out of the furnace in a soft, pasty condition suitable for immediate working. ”

“ Ores of Iron.—Even though the earth seems to be a huge iron meteor with but a thin covering of rocks, the exasperating proneness of iron to oxidize explains readily why this metal is only rarely found native, except in the form of meteorites. They are four important iron ores, magnetite, haematite, limonite and siderite, and one of less but still considerable importance, pyrite or pyrites.
44. Magnetite, Fe3O4, contains 72.41% of iron. It crystallizes in the cubical system, often in beautiful octahedra and rhombic dodecahedra. It is black with a black streak. ”

“ There are many deposits of magnetic oxide or iron in nature which are almost chemically pure. By applying the thermit process to this, it may be as little as a pound or two mixed with powdered aluminum in a crucible and starting the ignition, the metal oxide will be reduced and made liquid, so that it can be cast in a mold, and you can have a piece of almost chemically pure iron, so soft, because of its purity, that, as the metallurgist says, it can be cut with a knife—but if you will believe the writer, it cannot be cut to any considerable depth. ”

“ Iron seems to be a metal that proves active in its metallic state; its filings may be given in the form of powder, conjoined to some aromatic, or what is perhaps more eligible, in the form of an electuary. The Mahometan practitioners are in the habit of prescribing them, in conjunction with ginger, and cummin seeds, in cases requiring tonics. Dose, grs. v to ʒss. Impurities. Iron filings should be carefully purified by the application of the magnet, since those obtained from the work-shops are generally mixed with copper and other metals. ”

“ They enter most often into the truer and more homogeneal substance of the globe, and in the process of time a vein of iron results; loadstone is also produced, which is nought else than a noble kind of iron ore: and for this reason, and on account of its substance being singular, alien from all other metals, nature very rarely, if ever, mixes with iron any other metal, while the other metals are very often minutely mixed, and are produced together. ”