Joseph John Thomson,
Rays of Positive Electricity and Their Application to Chemical Analyses…
(1913)
“ The pressures at which spectroscopic observations have been made are so high that an atom is continually passing backwards and forwards between the neutral and charged conditions. It is thus a matter of great difficulty to determine whether the atom emits the lines in one state or the other, and there Is, I think, at present no experiment which is absolutely decisive between the two views. Thus, for example, it is found that the Doppler effect is increased when the positive rays are exposed to an accelerating potential after passing through the cathode. ”
