Iron core

“ Billy looked at him questioningly.
“That was rather technical, wasn’t it, Billy? You see, I was talking to a technical man. Just between you and me, meteoric iron comes down from the sky, from what we call shooting stars. Sometimes large pieces are found. I suppose that much of it falls into the sea. It is the purest iron that has ever been found.”
“What about magnetic iron?” asked Dr. Crandon. “Where does that come from?”
“At the present time,” answered Mr. Prescott, “most of it comes from Sweden and Norway. It makes the best kind of steel. ”

“ The reduction of the ores of iron into metallic iron is in principle very simple, because when the oxides of iron are strongly heated with charcoal, hydrogen, carbonic oxide, and other reducing agents, [5] they easily give metallic iron. But the matter is rendered more [322] difficult by the fact that the iron does not melt at the heat developed by the combustion of the charcoal, and therefore it does not separate from those mechanically mixed impurities which are found in the iron ore. ”

“ Iron is magnetic up to a dull-red heat, at which point it loses all traces of that property. It melts at about 3300° Fahr. With oxygen, chlorine, iodine, the acids, &c., it forms numerous important compounds. As a remedial agent, when properly exhibited, iron acts as a genial stimulant and tonic, and generally proves beneficial in cases of chronic debility, unaccompanied with organic congestion or inflammation. The carbonate (ferrous carbonate) , as it exists in mineral waters, held in solution by carbonic acid in excess, appears to be the form most congenial to the human body ”

“ We know that iron is a chemical element—the chemists write it Fe for short, after the Latin word "ferrum," meaning iron—it is one of those substances which cannot be separated into anything else but itself. It can be made to join with other elements; for instance, it joins with the oxygen in the air and forms scale or rust, substances known to the chemist as iron oxide. But the same metal iron can be recovered from that rust by abstracting the oxygen; having recovered the iron nothing else can be extracted but iron; iron is elemental. ”

“ During the melting of the charge the heat is kept as high as possible and the molten iron is “puddled,” i. e., stirred, by the “puddler” or his helper with a “rabbler” or iron bar. In order to take out the phosphorus and sulphur, which for best results should be removed before the carbon is eliminated, the heat of the furnace is lowered somewhat as soon as all of the pig has melted, and some iron oxide is mixed into the “bath” of molten iron and cinder. Most of the phosphorus and sulphur are chemically acted upon and pass into the cinder which covers the iron. ”

“ The iron rapidly melts and saturates itself with carbon. After a few minutes’ heating to a temperature above 4000° C.—a temperature at which the iron melts like wax and volatilises in clouds—the current is stopped and the dazzling fiery crucible is plunged beneath the surface of cold water, where it is held till it sinks below a red heat. As is well known, iron increases in volume at the moment of passing from the liquid to the solid state. The sudden cooling solidifies the outer layer of iron and holds the inner molten mass in a tight grip. ”

“ Soft iron is characterised by its attaining a fibrous fracture after forging, whilst tough iron preserves its granular structure after this operation. Certain sorts of iron, although fairly soft at the ordinary temperature, become brittle when heated and are difficult to weld. These sorts are less suitable for being worked up into small objects. The variety of the properties of iron depends on the impurities which it contains. In general, the iron used in the arts still contains carbon and always a certain quantity of silicon, manganese, sulphur, phosphorus, &c. ”

“ Hardly a step of our progress or an incident of our civilization has not in one way or another been influenced by the properties of iron and steel. It is remarkable that these properties have been determined by the relations subsisting between a mass of iron, itself protean in its nature, and the few tenths per cent of carbon it contains. ”

“ Again, iron which has been excited by a loadstone, * if that iron on account of obstacles should not be able to turn round immediately in accordance with its nature, as happens with a versorium, is laid hold of, when a loadstone approaches, on either side or at either end. Because, just as it can implant, so it can suddenly change the polarity and turn about the formal energies to any part whatever. So variously can iron be transformed when its form is adventitious and has not yet been long resident in the metal. ”

“ Pure iron is a chemical curiosity which looks very much like silver. As obtained from its ores, or as it occurs in Nature, iron always has some impurities with it, such as carbon, silicon, sulphur and phosphorus, and these are highest in the crudest iron such as “pig-iron.” Its malleability and ductility are only a little less than for gold and silver, and so it has a wide range of qualities for use by man. It is only rarely found native in minute grains in some of the dark lavas. ”

“ Thus the molecule of the red matter of the blood contains, for each atom of iron, 712 atoms of carbon, 1,130 of hydrogen, 214 of nitrogen, 245 of oxygen, and 2 of sulphur, or 2,303 atoms in all. Existing in compounds of so complex composition, iron can be present only in very small proportions to the whole. Though an essential element, there is comparatively but little of it. The whole body of man does not contain more than one part in twenty thousand of it. ”

“ Ordinary cast iron, while strong and hard enough for many purposes, still is brittle by reason of the large proportion of carbon and other impurities which it contains. These impurities may be burned out in the puddling process, and the nearly pure iron thus obtained, called malleable or wrought iron, has a toughness enabling it to resist far greater strains than cast iron can stand. Intermediate between the two irons, and containing one per cent of carbon, more or less, is still another product, steel, which may be made even more tenacious than wrought iron, or even harder than cast iron. ”

“ Of the iron-carbon alloys of compositions lying to the right of the line UV, we find the case to be different, for each one of them has more than the 1.7% of carbon which is the maximum amount which “gamma” iron can retain. Now the lowest temperature at which any iron-carbon alloy can exist without freezing is slightly above 2066° F., and there is but one composition—95.7% of iron and 4.3% of carbon—which can survive until this low temperature is reached. ”

“ Crandon, “from fishing ore with tongs.”
“We’ve moved along a great way since that time,” said John Bradford, “and most of our progress has been due to iron.”
“Giants don’t do all the work even now,” said Mr. Prescott. “They make short work of iron mountains and surface deposits, but most of them are too large to work underground; though we mustn’t forget that Giant Electricity works down there with the men.
“Giant Gravity helps too, for, when they work below the deposit, he caves the ore down. ”

“ For the iron is not taken possession of and allured by material effluvia, after the manner of electricks, but only by the immaterial action of its form or an incorporeal progression, which in a piece of iron as its subject acts and is conceived, as it were, in a continuous homogeneous body, and does not need more open ways. ”

“ No search was made for other tissues or organs presenting more favorable conditions, for no others were known that had iron in themselves. The liver and the spleen were supposed to receive it from the blood under the complicated form in which it exists there, or under some equivalent form. It was not, therefore, supposed till within a very few years that the two conditions were realized in any organ that were required to secure a slow combustion by iron—that is, combinations resembling ferrous and ferric salts with a weak acid and a source of oxygen. ”

“ Open-hearth iron is practically pure iron, having no constituents or slag inclusions which materially affect its properties.
2. Wrought iron, for all practical purposes, is pure iron 86except for its content of slag. It is the only one of the iron family which does normally contain slag.
3. Neither open-hearth iron nor wrought iron contains carbon in appreciable quantities.
4. The distinguishing and active element of the steel family is carbon. With increase of carbon the hardness of the alloy increases as does its tensile strength, but the ductility (elongation or stretch) decreases. ”

“ It is so highly 75refined that it can hardly be called steel at all but is often called “open-hearth iron” or “ingot iron.” It is probably the purest iron on the market in commercial quantities to-day. While in the chemical laboratory iron of considerably greater purity can be made, for a commercial product this is remarkably pure, seldom containing more than 1⁄4 per cent of elements other than the metal, iron. ”

“ Iron contains in its ores many impurities of different natures, according to circumstances, and is in its preparation exposed to several others; by these its quality is frequently much affected. Its valuable ores all contain the iron in the state of oxide. The oxygen, it is generally believed, is not wholly separated even in the best malleable iron, but enough still remains to impair in some degree its good qualities. In its manufacture it is exposed to the action of carbon, with which it is capable of combining. ”

“ We have long known that carbon has forms which vary as widely as coal, graphite and the diamond. Many other elements are detected in a similar masquerade. Iron, for instance, takes three forms, alpha, beta, and gamma. Alpha iron is soft, weak, ductile and strongly magnetic; beta iron is hard, brittle and feebly magnetic; gamma iron is also hard and feebly magnetic, yet ductile. Joule, the famous English experimenter, prepared an amalgam of iron with mercury ”

“ Water saturated with fixed air dissolves iron, and makes a pleasant chalybeat.
The calx of iron gives a green colour to glass.
[Pg 107] Iron readily combines with sulphur. When they are found combined by nature, the substance is called pyrites.
The union of phosphoric acid with iron makes it brittle when cold, commonly called cold short; and the union of arsenic makes it brittle when hot, thence called red short.
Iron unites with gold, silver, and platina, and plunged in a white heat into mercury, it becomes coated with it ”

“ With mercury iron refuses to combine directly, the iron amalgam that has been used for electrical machines being made by a somewhat complicated process with the aid of the amalgam of sodium. When immersed in fuming nitric acid, iron becomes coated with insoluble oxide, and as it then refuses to dissolve in acids (unless the coating be removed) , it is said to be in a passive state. Dry air or oxygen gas has no effect on iron. The ‘rusting’ of iron in ordinary atmospheric air is due to the presence of moisture ”

“ Cold iron, however, cannot retain in the chemically combined form as much carbon as does molten iron, so, during the solidification and cooling of the alloy, more or less of its carbon was precipitated, i.e., thrown out of solution and from chemical combination with the iron, the amount depending mainly upon the speed of the cooling. ”

“ The latter salt, under the combined influence of hydrogen and heat, is reduced to metallic iron, which assumes the appearance of a fine black powder. When the experiment is completed the glass vessel is closed, and the iron, thus protected from contact with the air, can be preserved indefinitely; but if it is exposed to the air by breaking off the end of the receptacle (fig. 311) , it ignites immediately, producing a shower of fire of very beautiful effect. Iron thus prepared is known under the name of pyrophoric iron. Iron is acted upon in a very powerful manner by most acids. ”

“ That is, as soon as a vessel costing millions of dollars leaves the docks, she enters into active competition for a place on the junk pile."
The greatest improvement that can be imagined in the iron situation will be in the discovery and use of alloys or mixtures of iron with other materials. Steel, the strongest of all forms of iron, is an alloy of iron and carbon, and for various purposes these are further mixed with nickel and silicas. Many other alloys have been discovered within the last few years, and each makes possible new uses for iron requiring greater strength. ”

“ Wrought iron is softer than cast iron, and, being pure iron, is more liable to be corroded by the action of the atmosphere and products of combustion of the powder; it possesses also considerable ductility. The tensile strength of wrought iron, which under the most favorable circumstances is double that of the best cast iron, depends on the character of the crystalline structure, and the manner of applying the tensile force, or in other words, wrought iron offers the greatest resistance to a force of extension when the structure is fibrous, and the force acts in the direction of the fibres. ”

“ Similar alloys of iron with the other elements mentioned are made in an electric furnace by reducing the mixed oxides with carbon.
Pure iron. Perfectly pure iron is rarely prepared and is not adapted to commercial uses. It can be made by reducing pure oxide of iron in a current of hydrogen at a [Pg 349] high temperature. Prepared in this way it forms a black powder; when melted it forms a tin-white metal which is less fusible and more malleable than wrought iron. It is easily acted upon by moist air.
Compounds of iron. ”