Melting point

“ Some have even assumed the melting point to be less than thirty miles, when “the next contiguous matter is in a state of fusion, at a temperature probably higher than any that man can produce by artificial means, or any natural heat that can exist on the surface.” ”

“ If the mean annual temperature be 20° F., and the mean winter temperature be −12° F., as in parts of Greenland, all the ice must be considerably below the melting point, since the pressure of ice a mile in depth lowers the melting point only to 30° F., and the earth-heat is only sufficient to melt 1/4 in. ”

“ From this it is apparent that the stable modification at temperatures in the neighbourhood of the melting point is that which is in equilibrium with the liquid phase at the natural freezing point.
From what has been said, it will be easy to predict what will be the behaviour of the system under different conditions. If pure α is heated, a temperature will be reached at which it will melt, but this melting point will be sharp only if the velocity of isomeric transformation is comparatively slow; i.e. slow in comparison with the determination of the melting point. ”

“ Where can it get this
heat? We assume that we give it none. It has only two sources,
the ice can take heat from itself, and it can take heat from the
water. It does both in this case, and both ice and water drop in
temperature. They fall in temperature till -7.5° is reached. Then
the ice has got to its melting point under the pressure of one
thousand atmospheres, or, as we may put it, the water has reached
its freezing point. There can be no more melting. ”

“ This temperature is somewhat different from the ordinary melting-point, the latter corresponding to atmospheric pressure, the former to the maximum vapour-pressure; and so we come to a third relation for polymorphism. Just as the melting-point changes with pressure, the transition-point also changes; even the same quantitative relation holds for both, as L. J. Reicher proved with sulphur: aT/aP = AvT/q, v being the change in volume which accompanies the change from rhombic to prismatic sulphur, and q the heat absorbed. ”

“ The ridging up of any part of the terrestrial crust will afford some relief from pressure to the parts of the interior immediately underneath. If, as is probable, the material of the earth's interior is at the melting point proper for the pressure at each depth, then any diminution of the pressure may allow the intensely heated substance to pass into the liquid state. ”

“ During that time the heat must accumulate to almost the melting point of lead; while, on the other hand, the absence of the sun for an equal period must be followed by a period of intense cold, such as we have no experience of, even in the Arctic regions. ”

“ When freezing occurs, however, the temperature rises to and remains at the true melting point, and an increase of deflection following a gradual fall always indicates overcooling. The higher deflection then attained is the true freezing point. Antimony frequently overcools to 600° before freezing, but on setting rises to the correct figure—631°. ”

“ At such depths, however, the downward pressure upon the rocks is so great that their melting points are notably raised, and there is every reason to believe that under ordinary conditions the rocks 20 to 35 miles down are not molten. If we adhere to the older (nebular) hypothesis of earth origin, the interior heat of the earth is left over from the cooling, once molten, earth. On the basis of another (planetesimal) hypothesis, the earth’s heat is due to the steady, powerful action of gravity causing the earth to contract. ”

“ The fire which is hot enough to melt a lump of ice may not be hot enough to melt an iron poker; on the other hand, it may be sufficiently hot to melt a tin spoon. Different substances melt, or liquefy, at different temperatures; for example, ice melts at 0° C., and tin at 233° C., while iron requires the relatively high temperature of 1200° C. Most substances have a definite melting or freezing point which never changes so long as the surrounding conditions remain the same. ”

“ This process is the exact opposite of the formation of ice by evaporation; it is the atmosphere which is made humid by the vaporizing of the ice, and by the drip. When the air is thoroughly saturated with the vapor, being scarcely renewed from outside and but a few degrees above freezing point, it undoubtedly retards evaporation, acts like a blanket and lessens the rate of melting of the ice. ”

“ Whenever, by the melting of the lower portion of any part of a glacier, a piece of it cracks and falls to a lower level, the friction of the broken sides will produce heat, and melt a small portion of water. This water, trickling down very slowly, will form a thin layer on the broken surface, and a portion will be retained in the narrowest part of the crack. But, since the temperature of a glacier is very near the freezing point, that water will freeze very slowly. ”

“ Each has its own natural melting and vaporizing point, so that while the blend remains fairly uniform it may tend to lose some constituent while molten, or in cooling to promote the crystallization of another, if held too near its particular freezing point. ”

“ Although this sphere has already lost a large part of the heat with which it was in the beginning endowed, it is still very hot in its deeper parts, as is shown by the phenomena of volcanoes. This internal heat, which to the present day at the depth of a hundred miles below the surface is probably greater than that of molten iron, [Pg 89] is constantly flowing away into space; probably enough of it goes away on the average each day to melt a hundred cubic miles or more of ice, or, in more scientific phrase, the amount of heat rendered latent by melting that volume of frozen water. ”

“ The result is that a snow coating is in effect an admirable blanket. When the sun shines upon it, much of the heat is reflected, and as the temperature does not penetrate it to any depth, only the superficial part is melted. This molten water takes up in the process of melting a great deal of heat, so that when it trickles down into the mass it readily refreezes. ”

“ It is probable that melting is much more nearly continuous in the body of a moving ice sheet than at its surface, and that some of the water thus produced sinks to the bottom of the ice without refreezing. At the base of the ice, so long as it is in movement, there is doubtless more or less melting, due both to friction and to the heat received by conduction from the earth below. Thus in the ice and under the ice there must have been more or less water in motion throughout essentially all the history of an ice sheet. ”

“ If, on the other hand, the temperature over and about the ice field be lowered, melting will be diminished, and if the rate of movement be constant, the edge of the ice will advance farther than under the earlier conditions of temperature, since it has more time to advance before it is melted. ”

“ The process of melting ice is very slow, because every portion must absorb or render latent a certain quantity of heat before it can take the liquid state—hence the difficulty of melting blocks of ice when they are surrounded with non-conducting materials ”

“ The slowness of the thawing will surprise most people who have not previously tried the experiment. It takes about as long to melt this snow as it would to raise an equal weight of water from 32° to 174°. Or, if a pound of water at 174° be mixed with a pound of snow at 32°, the result will be two pounds of water at 32°; 142° will have disappeared without making the snow any warmer, it will all have been used up in doing the work of melting. ”

“ The transition of water to ice, and of ice to water, produces important changes in the temperature of surrounding objects. We are often made painfully sensible of the chilling influence of the atmosphere when its heat is rapidly abstracted in the melting of large masses of ice and snow. But the reverse of this takes place in freezing. The crystallization of water is attended with an elevation of temperature. The heat which vapor carries with it in its aërial journeys is liberated when those vapors are transformed into flakes of snow. ”

“ These masses of liquid rock would also tend to melt their own way upward, especially when given a lift by gases; for gases would be given off, also, in this heating and melting process, and tend to work their way toward the surface, carrying with them the liquid rock.
5. Now the greater the pressure under which a thing is kept the more difficult it becomes for it to flow; the less the pressure the more easily it flows and the longer it remains in the fluid state. So as it rose fluid rock would require less heat to keep it fluid and would have more heat left over for melting its way up. ”

“ At that temperature, therefore, the internal motion, occasioned by the increased specific gravity of the condensed particles, ceases; for when the water at the surface no longer condenses, it will no longer descend, and leave a fresh surface exposed to the atmosphere: this surface alone, therefore, will be further exposed to its severity, and will soon be brought down to the freezing point, when it becomes ice, which being a bad conductor of heat, preserves the water beneath a long time from being affected by the external cold. ”

“ So, the heat that has been applied to the melting ice has been utilized during the process of its liquefaction in rearranging the water molecules and putting them in a state of strain, so to speak, like the weight that is wound up to a certain height. There is a certain amount of potential energy that is stored in the molecules of water that will be given up and become active energy in the form of heat, if the water is again frozen. ”

“ When the ice is all melted potential energy is no longer stored, but is manifested in the sensible heating of water, the degree of which is measurable by the thermometer, until it reaches the boiling point, where it is again arrested. All of the surplus heat above that temperature is consumed in rending the liquid water into moisture globules that float away into the air, each one of them charged with a store of potential energy. Let us follow this vapor spherule as it floats into the upper regions of the atmosphere. ”

“ The conditions favorable to glaciation are, therefore, heavy precipitation and low annual temperature. If the precipitation is scanty, the small snowfall is soon melted; and if the temperature be too high, the moisture is precipitated not in the form of snow but as rain. It is important here to keep in mind that snow is a poor heat conductor and itself protects its deeper layers from melting. ”

“ Ice charged with water is potentially, but not sensibly, warmer than ice which has just reached the melting temperature.
The warm wave of conduction dies out below like the cold wave. The warm wave descending by the flow of water stops where the freezing temperature of water is reached. In regions where the average temperature is below freezing, the water-wave does not descend so far as the wave of conduction, since the latter descends below the zone where the melting temperature is found. ”

“ This heat is relative, and though it be imparted to air far below the freezing-point, raising its temperature only a few degrees, its expansive power for that change is as great when those few degrees are low down as it is when they are high up on the scale. If such condensation of vapour do take place, then liberation of heat and expansion of air must follow, and consequently the oblateness of the atmospherical covering of our planet will be altered ”

“ Now, let us suppose, what nearly everyone acknowledges to be true, that the earth was originally so hot as to be a molten globe, and that while in this molten condition, it began to revolve or move around the sun. Since the empty space through which the earth moves is very cold, something in the neighborhood of 45° below the [Pg 170] zero of the Fahrenheit thermometer scale, the loss of heat would take place very rapidly and a thin crust of hardened materials would be formed on the outside. Now all the time the earth is cooling, it is shrinking or growing smaller. ”

“ Several results of the gradual cooling of the Earth—as the formation of a crust, the solidification of sublimed elements, the precipitation of water, &c., have been already noticed—and I here again refer to them merely to point out that they are simultaneous effects of the one cause, diminishing heat. Let us now, however, observe the multiplied changes afterwards arising from the continuance of this one cause. The Earth, falling in temperature, must contract. Hence the solid crust at any time existing, is presently too large for the shrinking nucleus ”

“ Nevertheless it will be clear that the presence of scattered rock débris on a glacier must greatly augment the rate of melting, as it fairly honeycombs the ice and increases the number of melting surfaces. Wherever the débris is dense, on the other hand, and accumulates on the glacier in a heavy layer, its effect becomes a protective one and surface melting is retarded instead of accelerated. ”

“ Naturally when the ice stream reaches the lower and warmer altitudes, melting goes on more rapidly, until finally the end of the ice wastes away, and a stream or river ensues. Now, it is for only a very short time in each year, in the latitude that we are considering, that the temperature is such that the amount of daily melting of ice exactly corresponds with the daily advance produced by the flow of the glacier. ”