Magnesium chloride

“ The solidified chloride is then broken up, the shots and fused masses of magnesium are picked out, run together in a plumbago crucible without flux, and poured into a suitable mould. Smaller pieces are thrown into a bath of melted carnallite and pressed together with an iron rod, the bath being then heated until the globules of metal float to the top, when they may be removed in perforated iron ladles, through the holes in which the fused chloride can drain away, but through which the melted magnesium cannot pass by reason of its high surface tension. ”

“ The most important of the halide salts is the chloride which, in the hydrated form, has the formula MgCl2·6H2O. It may be prepared by dissolving the metal, its oxide, hydroxide, or carbonate in dilute hydrochloric acid, or by mixing concentrated solutions of magnesium sulphate and common salt, and cooling the mixture rapidly, when the less soluble sodium sulphate separates first. It is also formed as a by-product in the manufacture of potassium chloride from carnallite. The hydrated salt loses water on heating, and partially decomposes into hydrochloric acid and magnesium oxychlorides. ”

“ Acidity will occur where sea water is present in a boiler. There is the possibility of such an occurrence in marine practice and in stationary plants using sea water for condensing, due to leaky condenser tubes, priming in the evaporators, etc. Such acidity is caused through the dissociation of magnesium chloride into hydrochloride acid and magnesia under high temperatures. The acid in contact with the metal forms an iron salt which immediately upon its formation is neutralized by the free magnesia in the water, thereby precipitating iron oxide and reforming magnesium chloride. ”

“ The point of maximum solubility is about 95° Fahr. The presence of magnesium chloride, or of calcium chloride, in water, diminishes its power of dissolving sulphate of lime, while the presence of sodium chloride increases that power. As an instance of the latter fact, we find a boiler works much cleaner which is fed alternately with fresh water and with brackish water pumped from the Tyne when the tide is high than one which is fed with fresh water constantly. ”

“ The bicarbonate of magnesium (magnesiæ bicarbonas, L.) exists only in solution. The so-called ‘fluid magnesias’ of Murray, Dinneford, Husband, &c., are solutions of this salt. The small prismatic crystals which are deposited when ‘fluid magnesia’ is exposed to the air for some time consist of hydrated neutral carbonate, and not bicarbonate, as is sometimes stated.
Magnesium, Chloride of. MgCl2. Syn. Magnesii chloridum, L. Prep. (Liebig.) ”

“ The hydrogen and magnesium go to the negative pole; this last decomposes the water and forms magnesium oxide, whilst the hydrogen is disengaged. If in this liquid coloured vegetable fibre is introduced, the oxygen compound acts on the colouring matter, oxidising it. Chlorine combines with the hydrogen to form hydrochloric acid, which finding itself in the presence of magnesium in the liquid combines with it, and forms the initial chloride of magnesium. ”

“ In the first place it may be again noted that at a temperature above 167.5° (point M) carnallite cannot exist. If, therefore, a solution of magnesium and potassium chlorides is evaporated at a temperature above this point, the result will be a mixture of potassium chloride and either magnesium chloride tetrahydrate or magnesium chloride dihydrate, according as the temperature is below or above 176°. The isothermal curve here consists of only two branches. ”

“ The liquid is next pumped into the settlers, in which it deposits its ferric and aluminic oxides and sulphate of lime. The clear liquor containing the chlorides of manganese and magnesia is then run into an iron evaporating pan, where it is concentrated by boiling until it reaches a temperature of between 300° and 320° F. At this point the magnesium chloride begins to be decomposed by the water, and hydrochloric acid is given off. When it has reached the above degree of concentration, it is conveyed into a muffle furnace. ”

“ Marine salt is not the only substance dissolved in the water, but is accompanied by several other bodies, the principal of which is chloride of magnesium. This salt when dry resists the action of the most violent heat without changing; but in boiling water undergoes a double decomposition, in which the chlorine leaves the magnesium to unite with the hydrogen of the water, while the oxygen thereof unites with the magnesium. There is thereby produced magnesia, which remains in the vessel, and hydrochloric acid, which is distilled over. ”

“ The chloride of magnesium, or bittern, not only deteriorates the salt very much, but occasions a considerable loss of weight. It may, however, be most advantageously got rid of, and converted into chloride of sodium by the following simple expedient:—Let quicklime be introduced in equivalent quantity to the magnesia present, and it will precipitate this earth, and form chloride of calcium, which will immediately react upon the sulphate of soda in the mother-water, with the production of sulphate of lime and chloride of sodium. ”

“ In a 0.1 molar solution of magnesium sulphate, which is ionized to the extent of 37.3%, the concentration of magnesium-ion is 0.0373, and it would require a concentration greater than 2E−5 of hydroxide-ion to precipitate any magnesium hydroxide.349 Now, the concentration of the hydroxide-ion, in an ammoniacal solution, can easily be reduced far below this value by the addition of ammonium chloride, nitrate, sulphate or other readily ionizable ammonium salt to the solution, and then magnesium hydroxide will not be precipitated. ”

“ These movements continue in loops isolated and removed from the body and placed in m/6 NaCl, LiCl, Na2SO4, sodium citrate, etc., for varying periods of time. They continue far longer in NaCl than in any other solution. Calcium chloride inhibits these movements, as is the case also with magnesium chloride. It was found, [61] however, in making these experiments with isolated loops removed from the body, that with certain mixtures of NaCl or LiCl with CaCl2 or MgCl2, movements began after 20 or 25 minutes of a character differing entirely from the movements seen in pure NaCl. ”

“ Silver chloride and iodide approach the condition of equality, and are not decomposed by heat. The most stable oxides under the action of heat are those of magnesium, calcium, silicon, and aluminium, since they also approach the condition of equality. For the same reason hydriodic acid decomposes with greater facility than hydrochloric acid. Chlorine does not act on magnesia or alumina, but it acts on lime and silver oxide, &c. ”

“ In colour and lustre it resembles silver, but in chemical properties is more like zinc; its sp. gr. is only 1·743; it is malleable; fusible at a red heat, and can be distilled like zinc; unaffected by dry air and by cold water; burns with brilliancy when heated to dull redness in air or oxygen gas, yielding oxide of magnesium; inflames spontaneously in chlorine, yielding chloride of magnesium; it dissolves in the acids with the evolution of hydrogen gas, and pure salts of magnesium result. ”

“ Magnesium is objectionable because the particles of magnesia form a voluminous cloud, which tastes and smells unpleasantly and settles down on everything. Still, for those who wish to work with this substance, about 18 inches burnt close to the opal and moved about all over it will be about sufficient to obtain good results under above mentioned conditions. An ordinary oil lamp or gas may also be used, provided the light is diffused.
Only the bromide lantern plates are suitable for reduction, the exposure, especially with the chloride emulsions, being so long as to place them out of court. ”

“ The powder ground in water was, when treated with carbonic acid under a high pressure, soluble, magnesium bicarbonate being formed, the saturated solution of which contains 2·3 per cent. of magnesia, and has a specific gravity of 1·028. The solution of lead chloride contains 1 part of the salt in 126 parts of water; it is mixed [Pg 112] with a slight excess of the magnesium carbonate solution as quickly as possible. The liquid is drawn off from the mixing vessel into a large receiver in which a precipitate deposits, consisting of white lead and a little oxychloride. ”

“ Magnesia was confounded with lime until 1755, when J. Black showed that the two substances were entirely different; and in 1808 Davy pointed out that it was the oxide of a metal, which, however, he was not able to isolate. Magnesium is found widely distributed in nature, chiefly in the forms of silicate, carbonate and chloride, and occurring in the minerals olivine, hornblende, talc, asbestos, meerschaum, augite, dolomite, magnesite, carnallite, kieserite and kainite. ”

“ It is now made by electrolysis, but instead of using as the electrolyte the melted anhydrous chloride, which is difficult to obtain, the natural mineral carnallite is used. This is melted in an iron pot which also serves as the cathode in the electrolysis. A rod of carbon dipping into the melted salt serves as the anode. The apparatus is very similar to the one employed in the preparation of sodium.
Properties. Magnesium is a rather tough silvery-white metal of small density. Air does not act rapidly upon it, but a thin film of oxide forms upon its surface, dimming its bright luster. ”

“ Reduction of the oxide with magnesium is never complete, and the carbon method gives only a mixture of carbide and metal. Electrolytic methods give no better results, since the metal liberated at the cathode always encloses oxide and other impurities. Moissan and Hönigschmid in 1906, by heating the carefully purified [254] anhydrous chloride with sodium in a sealed glass tube from which air and moisture had been removed, claim to have obtained a product containing only 3 per cent. ”

“ If six hundred grams of this chloride of magnesium are mixed with one hundred grams of chloride of sodium, or kitchen salt, and the same quantity of fluoride of calcium and metallic sodium in small fragments, and the mixture is put into an earthenware crucible made red-hot, and heated for a quarter of an hour under a closed lid, we shall find on pouring out the fluid on to a handful of earth, that we have obtained instead of scoria, forty-five grams of metallic magnesium. ”

“ Chlorine does not occur free in nature, but its compounds are widely distributed. For the most part it occurs in combination with the metals in the form of chlorides, those of sodium, potassium, and magnesium being most abundant. Nearly all salt water contains these substances, particularly sodium chloride, and very large salt beds consisting of chlorides are found in many parts of the world. ”

“ The metal may be obtained by reduction of its oxide with magnesium. It combines with hydrogen to form a hydride. The salts are mostly of yellowish colour. The chloride, SmCl3·6H2O, is a deliquescent solid which when heated in hydrochloric acid gas to 180° C. yields the anhydrous chloride. ”

“ Vapour density determinations at 448° indicate a partial dissociation of the double molecule Fe2Cl6; on stronger heating it splits into ferrous chloride and chlorine. It forms red crystalline double salts with the chlorides of the metals of the alkalis and of the magnesium group. An aqueous solution of ferric chloride is used in pharmacy under the name Liquor ferri perchloridi; and an alcoholic solution constitutes the quack medicine known as “Lamotte’s golden drops.” Many oxychlorides are known ”

“ Its bitter taste is due to the presence of chloride of magnesium and the oily feeling is produced by the chloride of calcium, which it holds in solution. As is well known, the density is so great that it is practically impossible for man or beast to sink beneath its waters. ”

“ Calculate the volume of magnesium ammonium chloride solution ("magnesia mixture") required to precipitate the phosphoric acid, assuming 40 per cent P_{2}O_{5} in the apatite. Measure out about 5 cc. in excess of this amount, and pour it into the acid solution. Then add slowly dilute ammonium hydroxide (1 volume of strong ammonia (sp. gr. 0.90) and 9 volumes of water) , stirring constantly until a precipitate forms. Then add a volume of filtered, concentrated ammonia (sp. gr. 0.90) equal to one third of the volume of liquid in the beaker (Note 1) . Allow the whole to cool. ”

“ And the molecules containing the sequestered iron tend to stick to the outside of the red blood cells, which threw the whole test off.”
“As I understand it, then,” said Major Grodski, “the antidote for the ... uh ... chelating agent is magnesium?”
“That’s right,” said Dr. Petrelli, nodding. “The stuff prefers magnesium ions to ferrous ions. They fit better within the chelating ring. Any source of magnesium will do, so long as there’s plenty of it. MacNeil was using milk of magnesia, which is the hydroxide, for ‘gastric acidity’. It’s changed to chloride in the stomach. ”

“ The stronger the solution administered, the greater is the quantity of water that passes into the bowel, a fact to be borne in mind when the salt is administered for the purpose of draining superfluous fluid from the system, as in dropsy. The oxide and carbonate of magnesium are also invaluable as antidotes, since they form insoluble compounds with oxalic acid and salts of mercury, arsenic, and copper. ”

“ The other method by which nitrogen may be absorbed on a considerable scale is by the aid of magnesium. The metal in the form of thin turnings is charged into hard glass or iron tubes heated to a full red in a combustion furnace. Into this air, previously deprived of oxygen by red-hot copper and thoroughly dried, is led in a continuous stream. At this temperature the nitrogen combines with the magnesium, and thus the argon is concentrated. A still more potent absorption is afforded by calcium prepared in situ by heating a mixture of magnesium dust with thoroughly dehydrated quick-lime. ”