Chemical experiment

“ Expert Analysis.—A modification of this experiment is employed by experts to test for AS2O3 poisoning. The organs.— stomach or liver—are cut into small pieces dissolved by nascent Cl, or HClO, made from KC1O3 and HCl, and the solution is introduced into a H generator, as above. AS2O3 preserves the tissues it comes in contact with, for a long time, and the test can be made years after death. All the chemicals must be pure, since As is found in small quantities in most ores, and the Zn, HCl, and H2SO4 of commerce are very likely to contain it. ”

“ It embraces directions for making seventy-five experiments with different substances and chemical properties, including oxygen and the air, hydrogen and water, chlorine and the chlorine family, acids, bases, salts, sulphur, nitrogen, carbon, carbon dioxide and the carbonates, fermentation, potash, and problems to illustrate the law of definite proportions. A title is given to each experiment, suggesting what is to be proved by it; the details of the process are given, and the pupil is left to do the rest, entering his particular observations and conclusions on the blank page opposite the text. ”

“ I am receiving them on my hand: and you will perhaps think I am acting oddly in this experiment; but it is to shew you that we must not always trust to noise and sounds, but rather to real facts. [Exploding a bubble on the palm of his hand.] I am afraid to fire a bubble from the end of the pipe, because the explosion would pass up into the jar and blow it to pieces. This oxygen then will unite with the hydrogen, as you see by the phenomena, and hear by the sound, with the utmost readiness of action, and all its powers are then taken up in its neutralisation of the qualities of the hydrogen. ”

“ Of which is the sugar experiment an example? Metathesis is an exchange of atoms in two different compounds; it gives rise to still other compounds.
A chemical change may add something to a substance, or subtract something from it, or it may both subtract and add, making a new substance with entirely different properties. Sulphur and carbon are two stable solids. The chemical union of the two forms a volatile liquid. A substance may be at one time a solid, at another a liquid, at another a gas, and yet not undergo any chemical change, because in each case the chemical composition is identical. ”

“ This experiment is a demonstration of the heat and light which are evolved during chemical combination. The substance phosphorus has a great affinity for oxygen gas, and wherever it [5] can get it from it will, especially when aided by the application of heat. To perform this experiment, put half a drachm of solid phosphorus into a Florence oil-flask, holding the glass slantingly, that the phosphorus may not take fire and break the glass ”

“ Experiment 62.—Put 20 cc. of H2O in a receiver. With the forceps take a piece of Na, not larger than half a pea, from the naphtha in which it is kept, drop it into the H2O, and at once cover the receiver loosely with paper or cardboard. Watch the action, as the Na decomposes H2O. HOH + Na = NaOH + H. If the water be hot the action is so rapid that enough heat is produced to set the H on fire. That the gas is H can be shown by putting the Na under the mouth of a small inverted t.t., filled with cold water, in a water-pan. Na rises to the top, and the t.t. fills with H, which can be tested. ”

“ The facility with which chemical inquiries are carried on, and the simplicity of the apparatus, offer additional reasons, to those I have already given, for the pursuit of this science. It is not injurious to the health; the modern chemist is not like the ancient one, who passed the greater part of his time exposed to p. 174the heat and smoke of a furnace and the unwholesome vapours of acids and alkalies and other menstrua, of which, for a single experiment, he consumed several pounds. ”

“ We must note that such ionisation may be regarded as conferring
potential chemical properties upon the molecules of the gas and
upon the substance whence the electrons are derived. Similar
ionisation under electric forces enters, as we now believe, into
all the chemical effects progressing in the galvanic cell, and,
indeed, generally in ionised solutes.
An experiment will best illustrate the principles I wish to
remind you of. ”

“ We may see an analogy to this in the union of the two opposite classes of compounds, acids and bases, to form salts.
72. Neutralization.
Experiment 44.—Put into an evaporating-dish 5 cc. of NaOH solution. Add HCl to this from a t.t., a few drops at a time, stirring the mixture with a glass rod (Fig. 20) , and testing it with litmus paper, until the liquid is neutral, i.e. will not turn the test paper from blue to red, or red to blue. Test with both colors. If it turns blue to red, too much acid has been added; if red to blue, too much base. ”

“ Such a statement would be absurd; but it is hardly more so than the talk one occasionally hears about the uselessness of applying the results of chemical analysis to the living bodies which have yielded them. One fact, at 18any rate, is out of reach of such refinements, and this is, that all the forms of protoplasm which have yet been examined contain the four elements, carbon, hydrogen, oxygen, and nitrogen, in very complex union, and that they behave similarly towards several reagents. ”

“ These substances will arise as a result of normal chemical research. We admit they may multiply much more quickly if work is specially directed towards their discovery, but it is practically impossible to control such work. ”

“ The view long maintained—until late in the nineteenth century, in fact—that organic and inorganic chemistry are separated from each other by a wide gap, is no longer held. Hundreds of organic substances, some of them of great complexity, have been made in the chemist’s laboratory, and can now be classed as properly with inorganic as with organic substances. The gap has been closed, and there is now but one chemistry. Only the most intricate chemical compounds still lie beyond the chemist’s grasp, and the isolation of these may be at any time overthrown. ”

“ Hence, reactions between organic compounds, even when they are in solution, proceed very slowly unless carried on at high temperatures, under increased pressure, or under the influence of some catalytic agent. Even under the stimulation of these reaction-accelerating agencies, most chemical changes in organic compounds when carried on in the laboratory, require several hours or even days and sometimes weeks, for their completion. But when similar reactions take place in living organisms, they proceed with velocities which resemble those of inorganic compounds in the laboratory. ”

“ After becoming acquainted with the constituent elements of all the substances within our reach and the mutual relations of these elements, the remarkable transmutations to which the bodies are subject under the influence of the vital powers of plants and animals, became the principal object of chemical investigations, and the highest point of interest. A new science, inexhaustible as life itself, is here presented us, standing upon the sound and solid foundation of a well established inorganic chemistry. ”

“ In many of the processes the materials do not appear to the naked eye after their introduction into the first plant unit, being fed by gravity or pressure from one enclosed apparatus to another. It would be absolutely essential for any inspection to conduct chemical tests at the different stages. ”

“ But as soon as the solution is rendered stronger, or the solvent and the dissolved body are endowed with a mutual chemical affinity, chemical reactions set in. Part of the molecules of the dissolved body dissociate, and the atoms of which they were composed, on being set free, combine with the atoms of the solvent. Chemical forces, much more energetic than the physical forces, enter into play, and most complicated chemical reactions—the intensity of which may be judged of from the changes of temperature—begin. ”

“ The fundamental task of inorganic chemistry is still connected with the classification of elements and compounds. The investigation of the classification of carbon compounds forms the field of organic chemistry; while general or physical chemistry deals with the laws of reaction, and the influence of various forms of energy in furthering or hindering chemical change. ”

“ The most interesting and, in many respects, the most important, development of the last twenty-five years has been in electro-chemistry. Electro-chemical methods are now employed for the production of a large number of elements, such as the alkali and alkaline earth metals, copper, zinc, aluminum, chromium, manganese, the halogens, phosphorus, hydrogen, oxygen, and ozone; various chemicals, including the mineral acids, hydrates, chlorates, hypochlorites, chromates, permanganates, disinfectants, alkaloids, coal tar dyes, and various carbon compounds ”

“ The peculiar manner in which hydrogen gas appears to dissolve solid substances,—as iron, potassium, sodium, sulphur, phosphorus, selenium, and arsenic, may be explained by regarding the results as a manifestation of the powers of chemical affinity over the forms of bodies. In like manner, the solution of salt in water, or the mixture of alcohol in that fluid, may be viewed as chemical phenomena, although usually considered as simple cases of solution or mixture: alterations of temperature and other physical changes taking place in either. ”

“ Our chemists found that starting with simple substances they could, by proper means, combine them into molecules of greater complexity, and in so doing could make many of the compounds that had hitherto been produced only as a result of living activities. For example, urea, formic acid, indigo, and many other bodies, hitherto produced only by animals and plants, were easily produced by the chemist by purely chemical methods. ”

“ Now here is another chemical test which is very readily applied. [Some of the carbonic acid was poured from one vessel into another, and its presence in the latter shown by introducing into it a lighted taper, which was immediately extinguished.] You see from this result also that it gravitates. All these experiments show you that, tried by the balance, tried by pouring like water from one vessel to another, this steam, or vapour, or gas, is, like all other things, attracted to the earth. ”

“ The methods of chemical analysis may be classified according to the type of reaction: (1) dry or blowpipe analysis, which consists in an examination of the substance in the dry condition; this includes such tests as ignition in a tube, ignition on charcoal in the blowpipe flame, fusion with borax, microcosmic salt or fluxes, and flame colorations (in quantitative work the dry methods are sometimes termed “dry assaying”) ; (2) wet analysis, in which a solution of the substance is treated with reagents which produce specific reactions when certain elements or groups of elements are present. ”

“ When oxygen combines with a single element, what is the compound called? We have found that O makes up a certain portion of the air; later, we shall see how large the proportion is. Its tendency to combine with almost everything is a reason for the decay, rust, and oxidation of so many substances, and for conflagrations, great and small. New compounds are thusformed, of which O constitutes one factor. Water, H2O, is only a chemical union of O and H. Iron rust, Fe2O3 and H2O, is composed of O, Fe, and water. The burning of wood or of coal gives rise to carbon dioxide, CO2, and water. ”

“ In the processes of life, as far as we are enabled to trace them, we see actions going on which are referred to certain causes which we appear to explain. Thus, the combination of the oxygen of the air with the carbon of the blood is truly designated a case of chemical affinity; and we find that in endeavouring to imitate the processes of nature in the laboratory, we are, to a certain extent, successful. We can combine carbon and oxygen to produce carbonic acid; and we know that the result of that combination is the development of certain definite quantities of heat. ”

“ The example is typical: nature and art abound with cases where a little energy, rightly directed, controls energy vastly, perhaps infinitely, greater in quantity. Often in a chemical compound the poise of attraction is so delicate that it may be disturbed by a breath, or by a note from a fiddle, as when either of these induces iodide of nitrogen to explode. A beam of light works the same result with a mixture of chlorine and hydrogen. One of the most [338] familiar facts of chemistry is that a fuel, such as coal, may remain intact in air for ages. ”

“ May we not, therefore, conclude that the chemical action exhibited in a burning body is a development of some latent force, with which we are unacquainted, produced by the absorption of light;—that a repulsive action at first takes place, by which the hydrogen and carbon are separated from each other;—and that in the nascent state they are seized by the oxygen, and again compelled, though in the new forms of water and carbonic acid, to resume their chains of combining affinity? ”

“ Those of our readers who wish to try the experiments [258] we have described for themselves can obtain all the necessary substances, except the poisons, at any chemists and the quantities required will only be the smallest that can be obtained, in fact any reasonable-minded chemist would probably let a microscopist whom he knew have a few grains of a large number of chemical substances, suitable for this work, at the outlay of a few pence. The chlorides of gold and platinum we fear no one will give away. ”