Chemical reaction

“ Hence, reactions between organic compounds, even when they are in solution, proceed very slowly unless carried on at high temperatures, under increased pressure, or under the influence of some catalytic agent. Even under the stimulation of these reaction-accelerating agencies, most chemical changes in organic compounds when carried on in the laboratory, require several hours or even days and sometimes weeks, for their completion. But when similar reactions take place in living organisms, they proceed with velocities which resemble those of inorganic compounds in the laboratory. ”

“ How might NH4Cl be obtained from the NH4OH in the Woulff bottles? (6) Test the liquid in each bottle with red litmus paper. (7) Add some from the first bottle to 5 or 10 cc. of a solution of FeSO4 or FeCl2, and look for a ppt. State the reaction.
99. Formation.—Ammonia, hartshorn, exists in animal and vegetable compounds, in salts, and, in small quantities, in the atmosphere. Rain washes it from the atmosphere into the soil; plants take it from the soil; animals extract it from plants. Coal, bones, horns, etc., are the chief sources of it, and from them it is obtained by distillation. ”

“ Warm in a flame. If the metal is pure, no action takes place. Into another tube put 6 cc. HCl and add a similar leaf. Heat this also. There should be no action. Pour the contents of one t.t. into the other. Note the effect. Which is stronger, one of the acids, or the combination of the two? Note the odor. It is that of Cl. 3HCl + HNO3 = NOCl + 2H2O + Cl2. This reaction is approximate only. The strength is owing to nascent chlorine, which unites with Au. ”

“ For, even the preachers have begun to tell us that God is radium, or ether or some scientific compound, and that the worst we wicked ones may expect is a chemical reaction. ”

“ At least two or three weeks are well spent in studying fundamental chemical reactions as facts quite independent of any theories whatsoever, in order that the student may thoroughly appreciate the nature of chemical change and become familiar with enough characteristic and typical cases of chemical action so that the general laws of chemical combination by weight and by volume may be logically deduced and the atomic and molecular theories presented as based upon those laws. ”

“ The peculiar manner in which hydrogen gas appears to dissolve solid substances,—as iron, potassium, sodium, sulphur, phosphorus, selenium, and arsenic, may be explained by regarding the results as a manifestation of the powers of chemical affinity over the forms of bodies. In like manner, the solution of salt in water, or the mixture of alcohol in that fluid, may be viewed as chemical phenomena, although usually considered as simple cases of solution or mixture: alterations of temperature and other physical changes taking place in either. ”

“ May we not, therefore, conclude that the chemical action exhibited in a burning body is a development of some latent force, with which we are unacquainted, produced by the absorption of light;—that a repulsive action at first takes place, by which the hydrogen and carbon are separated from each other;—and that in the nascent state they are seized by the oxygen, and again compelled, though in the new forms of water and carbonic acid, to resume their chains of combining affinity? ”

“ Of which is the sugar experiment an example? Metathesis is an exchange of atoms in two different compounds; it gives rise to still other compounds.
A chemical change may add something to a substance, or subtract something from it, or it may both subtract and add, making a new substance with entirely different properties. Sulphur and carbon are two stable solids. The chemical union of the two forms a volatile liquid. A substance may be at one time a solid, at another a liquid, at another a gas, and yet not undergo any chemical change, because in each case the chemical composition is identical. ”

“ When oxygen combines with a single element, what is the compound called? We have found that O makes up a certain portion of the air; later, we shall see how large the proportion is. Its tendency to combine with almost everything is a reason for the decay, rust, and oxidation of so many substances, and for conflagrations, great and small. New compounds are thusformed, of which O constitutes one factor. Water, H2O, is only a chemical union of O and H. Iron rust, Fe2O3 and H2O, is composed of O, Fe, and water. The burning of wood or of coal gives rise to carbon dioxide, CO2, and water. ”

“ To take a simple example:—oxygen and hydrogen are two gases which may be mixed in all proportions at ordinary temperatures, and it is easy to show that the properties of the products are simply those of mixtures of the two free gases. If, however, an electric spark be passed through the mixtures, powerful chemical union ensues, with its concomitants, great evolution of heat and consequent rise of temperature, and a compound, water, is formed which presents physical and chemical properties entirely different from those of its constituents. ”

“ An experiment to prove that the atmosphere does consist of nitrogen and oxygen, may be prettily proved in the following simple manner: A glass marmalade jar, or a soup-plate filled with water, and a piece of phosphorus as large as a pea, are the only things necessary. Take very great care not to touch the phosphorus, for the heat of the hand is sufficient to set it on fire, and a terrible wound would be caused. ”

“ It brings home to me what an unstable chemical compound man is. Here are the stage accessories as good as ever, while the players have all split up into hydrogen and oxygen and nitrogen and carbon, with traces of iron and silica and phosphorus. ”

“ From the beginning to the end the student is surprised and delighted with the developments of the exact discrimination, as well as the power and capacity, which are displayed in various forms of chemical action. Dissolve two substances in the same fluid, and then, by evaporation or otherwise, cause them to reassume a solid form, and each particle will unite with its own kind, to the entire exclusion of all others. Thus, if sulphate of copper and carbonate of soda are dissolved in boiling water, and then the water is evaporated, each salt will be reformed as before. ”

“ Oxidation and reduction reactions are frequently met with in analysis, and we shall turn now to the consideration of such reactions, from the point of view of the modern theory of solution and the laws of equilibrium. ”

“ Remove the spoon from the flame, when the liquid will become a solid of a brilliant emerald green color, and so remain until its heat sinks nearly to that of boiling water, when suddenly a commotion will take place throughout the mass, beginning from the surface, and each atom, as if animated, will start up and separate itself from the rest, till in a few moments the whole will become a heap of powder. ”

“ Thus we find 'inflammable air* as the name for hydrogen, 'fixed air* for carbonic acid gas, and 'dephlogisticated marine acid air' for chlorin. That no better principle of classification of substances from a chemical standpoint than that of superficial outward appearance was demanded is not strange, when we recollect that at this period and, indeed, down to the close of the eighteenth century, the transmutation of metals was a popular belief of the common people and was not disproved by the chemist. ”

“ When this element, nitrogen, is combined with the wonderful variety of compounds formed by carbon, we have not only a great many intimately related yet distinct [100] substances, but compounds which readily change from one form to another. These are the distinctive qualities or conditions necessary, from a chemical standpoint, to make the processes of life possible. Protoplasm, which is the basis of all life, is formed by an intimate mixture of a number of complex chemical compounds, the chief elements of which are carbon, hydrogen, oxygen, and nitrogen. ”

“ In a mechanical mixture, as we have seen, the elements which are to react one upon another are brought together in separate bodies. In gunpowder, for example, the carbon is contained in the charcoal, and the oxygen in the saltpetre. But in a chemical compound, these elements are brought together in the same body. In a mechanical mixture, we may put what proportion of oxygen we please. But elements combine chemically only in certain definite proportions, so that in the chemical compound we can introduce only a certain definite proportion of oxygen. ”

“ The putrefaction of animal and other azotized bodies is a chemical process, by which they are gradually dissipated in a gaseous form, chiefly in that of carbonic acid and ammonia; now to convert the carbon of the animal substance into carbonic acid requires oxygen, and to convert the azote into ammonia requires hydrogen, which are the elements of water. ”

“ These gases are oxygen and hydrogen. Every atom of water consists of one part of the former gas and two parts by volume of the latter. This you may prove in the following way:
Buy a piece of sodium, a metal that must not be touched with the fingers, and thrust it into a small one-ounce jar half full of water; cork the jar tightly.
Through a hole in the cork pass a glass tube, the outer end being drawn in a flame to a fine point. Apply a light at the end of the tube. The escaping gas will catch fire and burn with a light blue flame. This gas is hydrogen. ”

“ Now this chemical action is set going exactly as it would be if I had lighted the candle, or as it is when the servant puts coals on and lights the fire: the substances wait until we do something which is able to start the action. Can anything be more beautiful than this combustion of charcoal in oxygen? You must understand that each of these little sparks is a portion of the charcoal, or the bark of the charcoal, thrown off white hot into the oxygen, and burning in it most brilliantly, as you see. ”

“ In the phenomena of light, with a spectroscope, a luminous gas is sympathetic with, and emits and absorbs, only particular kinds of luminous rays. In chemical action also, combustion excites combustion, ferment excites ferment, infection communicates infection, and the similar chemical change is transmitted from molecule to molecule. ”

“ Chemical energy, or the mutual attractions and repulsions of atoms, is even more powerful than that of molecules. It displays itself in their elective affinities, or what may be called the likes and dislikes, or loves and hatreds, of these ultimate particles. Perhaps the best illustration will be afforded by that ‘latest resource of civilisation,’ dynamite. This substance, or to give it its scientific name, nitro-glycerine, is composed of molecules each of which is a complex combination of nine atoms of oxygen, five of hydrogen, three of nitrogen, and three of carbon. ”

“ Experiment 62.—Put 20 cc. of H2O in a receiver. With the forceps take a piece of Na, not larger than half a pea, from the naphtha in which it is kept, drop it into the H2O, and at once cover the receiver loosely with paper or cardboard. Watch the action, as the Na decomposes H2O. HOH + Na = NaOH + H. If the water be hot the action is so rapid that enough heat is produced to set the H on fire. That the gas is H can be shown by putting the Na under the mouth of a small inverted t.t., filled with cold water, in a water-pan. Na rises to the top, and the t.t. fills with H, which can be tested. ”

“ There is nothing surprising in the fact that a new conception of the chemical element can arise from a re-study of the process of combustion, if we remember that it was the picture of combustion, characteristic of the spectator-consciousness, which determined the conception of the chemical element as it prevails in modern science. ”

“ He should also be made clearly to distinguish between the essential features of the process and the different accessories, which may be more or less accidental—such, for example, as the water used in determining the combination of iron and sulphur, or the flame which accompanies combustion.
After a clear conception has been gained of a chemical process, with its definite factors and definite products, we are prepared for the next important [Pg 252] step. Every chemical process obeys three fundamental laws:
The Law of Conservation of Mass. ”

“ The stability constants, and the concentrations of the components used, determine the limiting concentrations in which a given metal ion is capable of continued existence, and determine, therefore, the question whether an ionogen, of a given solubility, is capable of existence as a solid phase in a given system. ”

“ It embraces directions for making seventy-five experiments with different substances and chemical properties, including oxygen and the air, hydrogen and water, chlorine and the chlorine family, acids, bases, salts, sulphur, nitrogen, carbon, carbon dioxide and the carbonates, fermentation, potash, and problems to illustrate the law of definite proportions. A title is given to each experiment, suggesting what is to be proved by it; the details of the process are given, and the pupil is left to do the rest, entering his particular observations and conclusions on the blank page opposite the text. ”

“ Q. What are three of the peculiarities of chemical affinity? A. Each kind of atom has its peculiar chemical affinities. Each atom has a certain equivalence or atom-fixing power. Chemical changes produce striking results.
45. Q. What is the most common way of producing hydrogen? A. By bringing together sulphuric acid and zinc.
46. Q. What are some of the properties of hydrogen as a gas? A. It is colorless, odorless, tasteless, and, bulk for bulk, it is the lightest substance known in nature.
47. Q. What is the most interesting chemical property of hydrogen? A. Its power to unite with oxygen. ”